Abstract
The symmetry properties of adiabatic free energy surfaces, which describe redox and dissociative electron transfer reactions in systems of the type in situ STM, are investigated. A notion of an effective overvoltage, which is a generalization of a traditional overvoltage to the case where the bias voltage is other than zero, is introduced. Diagrams of kinetic modes, which describe processes that can occur in systems of the type in situ STM under consideration, are constructed in the space of model parameters. It is shown that, in some cases, with the bias voltage other than zero, there may emerge DKR of a sufficiently complicated structure with several critical regions.
Similar content being viewed by others
REFERENCES
Kuznetsov, A.M. and Ulstrup, J., Probe Microscopy, 2001, vol. 2, p. 187.
Hansen, A.G., Wackerbarth, H., Nielsen, J.U., Zhang, J., Kuznetsov, A.M., and Ul’strup, J., Elektrokhimiya, 2003, vol. 39, p. 117.
Kuznetsov, A.M., Sommer-Larsen, P., and Ulstrup, J., Surf. Sci., 1992, vol. 275, p. 52.
Schmickler, W. and Widrig, C., J. Electroanal. Chem., 1992, vol. 336, p. 213.
Schmickler, W., Surf. Sci., 1993, vol. 295, p. 43.
Friis, E.P., Kharkats, Yu.I., Kuznetsov, A.M., and Ulstrup, J., J. Phys. Chem. A, 1998, vol. 102, p. 7494.
Kuznetsov, A.M. and Ulstrup, J., J. Phys. Chem. A, 2000, vol. 104, p. 11531.
Zhang, J., Kuznetsov, A.M., and Ulstrup, J., J. Electroanal. Chem., 2003, vol. 541, p. 133.
Kuznetsov, A.M. and Ulstrup, J., J. Electroanal. Chem., 2004, vol. 564, p. 209.
Medvedev, I.G., Elektrokhimiya, 2005, vol. 41, no.3.
Kuznetsov, A.M. and Medvedev, I.G., Elektrokhimiya, 2001, vol. 37, p. 396.
Kuznetsov, A.M. and Medvedev, I.G., J. Electroanal. Chem., 2001, vol. 502, p. 15.
Medvedev, I.G., Elektrokhimiya, 2003, vol. 39, p. 49.
Kuznetsov, A.M., Medvedev, I.G., and Sokolov, V.V., Elektrokhimiya, 2003, vol. 39, p. 932.
Kuznetsov, A.M., Medvedev, I.G., and Sokolov, V.V., J. Electroanal. Chem., 2003, vol. 552, p. 231.
Kuznetsov, A.M., Medvedev, I.G., and Sokolov, V.V., J. Chem. Phys., 2004, vol. 120, p. 7616.
Medvedev, I.G., Elektrokhimiya, 2004, vol. 40, p. 539.
Kuznetsov, A.M. and Medvedev, I.G., Elektrokhimiya, 2005, vol. 41, no.3.
Anderson, P.W., Phys. Rev., 1961, vol. 124, p. 41.
Muscat, J.P. and Newns, D.M., Prog. Surf. Sci., 1978, vol. 9, p. 1.
Kuznetsov, A.M., J. Electroanal. Chem., 1983, vol. 159, p. 241.
Schmickler, W., J. Electroanal. Chem., 1986, vol. 204, p. 31.
Kuznetsov, A.M., Medvedev, I.G., and Ulstrup, J., Electrochem. Commun., 2000, vol. 2, p. 135.
Author information
Authors and Affiliations
Additional information
__________
Translated from Elektrokhimiya, Vol. 41, No. 4, 2005, pp. 419–432.
Original Russian Text Copyright © 2005 by Medvedev.
Rights and permissions
About this article
Cite this article
Medvedev, I.G. Symmetry properties of adiabatic free energy surfaces and a diagram of kinetic modes in the case of electrochemical tunneling microscopy of redox systems. Russ J Electrochem 41, 368–380 (2005). https://doi.org/10.1007/s11175-005-0078-z
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11175-005-0078-z