Advertisement

Russian Journal of Electrochemistry

, Volume 41, Issue 2, pp 113–117 | Cite as

On the asymmetry of thermodynamic fluctuations of the electrode potential

  • B. M. Grafov
Article

Abstract

The asymmetry of thermodynamic fluctuations of the equilibrium electrode potential and the asymmetry of thermodynamic fluctuations of the electrical double layer charge is characterized quantitatively on the basis of third-order noise spectra.

Key words

thermodynamic fluctuations electrode potential electrical double layer charge 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  1. 1.
    Schultse, J.W. and Staikov, G., Electrochim. Acta, 2003, vol. 48, p. 2851.Google Scholar
  2. 2.
    Ito, Ya., J. Electroanal. Chem., 2003, vol. 559, p. 1.Google Scholar
  3. 3.
    Rudoi, Yu.G. and Sukhanov, A.D., Usp. Fiz. Nauk, 2000, vol. 170, p. 1265.Google Scholar
  4. 4.
    The Collected Works of J. Willard Gibbs, New Haven: Yale Univ. Press, 1948, vols. 1 and 2.Google Scholar
  5. 5.
    Einstein, A., Izbrannye Sochineniya (Selected Opuses), Moscow: Nauka, 1966, vol. 3.Google Scholar
  6. 6.
    Landau, L.D. and Lifshits, E.M., Statisticheskaya fizika (Statistical Physics), Moscow: Nauka, 1964, pp. 412, 463.Google Scholar
  7. 7.
    Nyquist, H., Phys. Rev., 1928, vol. 32, p. 110.Google Scholar
  8. 8.
    Callen, H.B. and Welton, T.A., Phys. Rev., 1951, vol. 83, p. 34.Google Scholar
  9. 9.
    Bernard, W. and Callen, H.B., Rev. Mod. Phys., 1959, vol. 31, p. 1017.Google Scholar
  10. 10.
    Myunster, A., Termodinamika neobratimykh protsessov (Thermodynamics of Irreversible Processes), Moscow: Inostrannaya Literatura, 1962, p. 36.Google Scholar
  11. 11.
    Mak-Kombi, K., Zadachi po termodinamike i statisticheskoi fizike (Problems in Thermodynamics and Statistical Physics), Landsberg, P., Ed., Moscow: Mir, 1974.Google Scholar
  12. 12.
    Freeman, J.J., Principles of Noise, New York: Wiley, 1958.Google Scholar
  13. 13.
    Gupta, M.S., Proc. IEEE, 1982, vol. 70, p. 788.Google Scholar
  14. 14.
    Van Kampen, N.G., Stochastic Processes in Physics and Chemistry, Amsterdam: North-Holland Physics, 1984.Google Scholar
  15. 15.
    Van Kampen, N.G., J. Math. Phys., 1963, vol. 4, p. 190.Google Scholar
  16. 16.
    Yakimov, A.V., Belyakov, A.V., Petrov, M. Yu., and Vandamme, L.K.J., Proc. SPIE, 2003, vol. 5115, p. 40.Google Scholar
  17. 17.
    Smulko, J.M. and Kish, L.B., Proc. SPIE, 2003, vol. 5115, p. 92.Google Scholar
  18. 18.
    Yakimov, A.V., Belyakov, A.V., Moryashin, A.V., and Perov, M.Yu., Proc. 17 Int. Conf. on Noise and Fluctuations, Sikula, J., Ed., Prague, 2003, p. 71.Google Scholar
  19. 19.
    Grafov, B.M., Proc. SPIE, 2003, vol. 5115, p. 16.Google Scholar
  20. 20.
    Grafov, B.M., Proc. 17 Int. Conf. on Noise and Fluctuations, Sikula, J., Ed., Prague, 2003, p. 41.Google Scholar
  21. 21.
    Grafov, B.M., Elektrokhimiya, 2003, vol. 39, p. 469.Google Scholar
  22. 22.
    Grafov, B.M., Elektrokhimiya, 2003, vol. 39, p. 1116.Google Scholar
  23. 23.
    Stratonovich, R.L., Izv. Vyssh. Uchebn. Zaved., Radiofizika, 1970, vol. 13, p. 1512.Google Scholar
  24. 24.
    Malakhov, A.I., Kumulyantnyi analiz sluchainykh negaussovskikh protsessov i ikh preobrazovanii (A Cumulant Analysis of Random Non-Gaussian Processes and Their Transforms), Moscow: Sovetskoe Radio, 1978.Google Scholar
  25. 25.
    Rosenblatt, M. and Van Ness, J.W., Ann. Math. Stat., 1965, vol. 36, p. 1120.Google Scholar
  26. 26.
    Brillinger, D.R., Ann. Math. Stat., 1965, vol. 36, p. 1351.Google Scholar
  27. 27.
    Korn, G.A. and Korn, T.M., Mathematical Handbook, New York: McGraw-Hill, 1968.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • B. M. Grafov
    • 1
  1. 1.Frumkin Institute of ElectrochemistryRussian Academy of SciencesMoscowRussia

Personalised recommendations