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Russian Journal of Coordination Chemistry

, Volume 31, Issue 12, pp 894–898 | Cite as

Kinetics of the Acid-Base Interaction between Tetra(4-tert-butyl)phthalocyanine and Nitrogen-Containing Bases in Dimethyl Sulfoxide

  • O. A. Petrov
  • G. V. Osipova
  • A. S. Semeikin
  • B. D. Berezin
Article

Abstract

Specific features of the acid-base interaction of tetra(4-tert-butyl)phthalocyanine with cyclic and acyclic nitrogen-containing bases in dimethyl sulfoxide are studied. The effect of pK a of proton-withdrawing molecules, basicity of a medium, and steric screening of acidic NH centers on the kinetic parameters of formation of proton-transfer complexes stable in time is shown.

Keywords

Physical Chemistry Inorganic Chemistry Dimethyl Kinetic Parameter Sulfoxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • O. A. Petrov
    • 1
  • G. V. Osipova
    • 1
  • A. S. Semeikin
    • 1
  • B. D. Berezin
    • 1
  1. 1.Ivanovo State University of Chemical TechnologyIvanovoRussia

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