Russian Journal of Coordination Chemistry

, Volume 31, Issue 12, pp 894–898 | Cite as

Kinetics of the Acid-Base Interaction between Tetra(4-tert-butyl)phthalocyanine and Nitrogen-Containing Bases in Dimethyl Sulfoxide

  • O. A. Petrov
  • G. V. Osipova
  • A. S. Semeikin
  • B. D. Berezin


Specific features of the acid-base interaction of tetra(4-tert-butyl)phthalocyanine with cyclic and acyclic nitrogen-containing bases in dimethyl sulfoxide are studied. The effect of pK a of proton-withdrawing molecules, basicity of a medium, and steric screening of acidic NH centers on the kinetic parameters of formation of proton-transfer complexes stable in time is shown.


Physical Chemistry Inorganic Chemistry Dimethyl Kinetic Parameter Sulfoxide 
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Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • O. A. Petrov
    • 1
  • G. V. Osipova
    • 1
  • A. S. Semeikin
    • 1
  • B. D. Berezin
    • 1
  1. 1.Ivanovo State University of Chemical TechnologyIvanovoRussia

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