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Russian Journal of Coordination Chemistry

, Volume 31, Issue 9, pp 609–618 | Cite as

EPR Study of Covalent Bond in Transition Metal Complexes

  • V. I. Murav'ev
Article

Abstract

The results of a study of a covalent bond in the anitibonding and bonding states of d1 and d9 complexes obtained by analyzing the EPR and optical data are presented. The nature of the electron density delocalization in some of the complexes is discussed. The effect of the charge-transfer states on the covalent bond structure is considered. The vibronic effect on the ground state function is discussed. The electronic distributions determined from EPR spectra by different approximation methods are compared.

Keywords

Physical Chemistry Inorganic Chemistry Approximation Method Metal Complex Covalent Bond 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • V. I. Murav'ev
    • 1
  1. 1.Research and Production Enterprise “Izmeritel'”UlyanovskRussia

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