Skip to main content
SpringerLink
Log in

Iron(II) Octaphenyltetrapyrazinoporphyrazinate Extra Complexes: Synthesis and Some Properties

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Iron(II) octaphenyltetrapyrazinoporphyrazinate [Fe{PzPh2}4PA] · 2H2O and its water-soluble sulfo-substituted form [Fe{Pz(4-SO3HPh)2}4PA] · 2H2O were synthesized. The effect of a ligand extra coordination on the spectral properties of sulfo-substituted iron(II) porphyrazinate was studied. The EPR and 17O NMR methods showed that in an alkaline medium, one-electron reduction of iron(II) complex results in the formation of a stable pentacoordinated anionic complex.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Gregory, P., J. Porphyrins Phthalocyanines, 2000, vol. 4, no.4, p. 377.

    Google Scholar 

  2. The Phthalocyanines. Properties and Applications, vols. 1–4, Leznoff, C.C. and Lever, A.B.P., Eds., New York: VCH Publishers, 1989.

    Google Scholar 

  3. De la Torre, G., Vazques, P., Adullo-Lopez, F., and Torres, T., J. Mater. Chem., 1998, vol. 8, no.8, p. 1671.

    Google Scholar 

  4. Tarasevich, M.S. and Radyushkina, K.A., Kataliz i elektrokataliz metalloporfirinami (Catalysis and Electrocatalysis with Metal Porphyrins), Moscow: Nauka, 1982.

    Google Scholar 

  5. Kudrik, E.V., Makarov, S.V., Zahl, A., and Eldik van, R., Inorg. Chem., 2003, vol. 42, no.2, p. 618.

    Google Scholar 

  6. Porfiriny: Spektroskopiya, elektrokhimiya, primenenie (Porfirins: Spektroskopy, Elektrochemistry, Applications) Askarov, K.A., Berezin, B.D., Bystritska, E.V., et al., Eds., Moscow: Nauka, 1987.

    Google Scholar 

  7. Ferraudi, G., Inorg. Chem., 1979, vol. 18, no.4, p. 1005.

    Google Scholar 

  8. Gunter, M.S. and Turner, P., Coord. Chem. Rev., 1991, vol. 108, no.1, p. 115.

    Google Scholar 

  9. Stuzhin, P.A., Hamdush, M., and Zeiner, U., Inorg. Chim. Acta, 1995, vol. 236, nos.1–2, p. 131.

    Google Scholar 

  10. Bauer, E.M., Ercolani, C., Galh, P., et al., J. Porphyrins Phthalocyanines, 1999, vol. 3, no.3, p. 371.

    Google Scholar 

  11. Liao, M.S. and Scheiner, S., J. Chem. Phys., 2001, vol. 114, no.22, p. 9780.

    Google Scholar 

  12. Yu, B.-S. and Goff, H.M., J. Am. Chem. Soc., 1989, vol. 111, no.17, p. 6558.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia

    E. V. Kudrik, V. N. Shishkin & G. P. Shaposhnikov

Authors
  1. E. V. Kudrik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. N. Shishkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. P. Shaposhnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 7, 2005, pp. 530–534.

Original Russian Text Copyright © 2005 by Kudrik, Shishkin, Shaposhnikov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kudrik, E.V., Shishkin, V.N. & Shaposhnikov, G.P. Iron(II) Octaphenyltetrapyrazinoporphyrazinate Extra Complexes: Synthesis and Some Properties. Russ J Coord Chem 31, 501–505 (2005). https://doi.org/10.1007/s11173-005-0126-y

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11173-005-0126-y

Keywords

Search

Navigation