Russian Journal of Coordination Chemistry

, Volume 31, Issue 7, pp 501–505 | Cite as

Iron(II) Octaphenyltetrapyrazinoporphyrazinate Extra Complexes: Synthesis and Some Properties

  • E. V. Kudrik
  • V. N. Shishkin
  • G. P. Shaposhnikov


Iron(II) octaphenyltetrapyrazinoporphyrazinate [Fe{PzPh2}4PA] · 2H2O and its water-soluble sulfo-substituted form [Fe{Pz(4-SO3HPh)2}4PA] · 2H2O were synthesized. The effect of a ligand extra coordination on the spectral properties of sulfo-substituted iron(II) porphyrazinate was studied. The EPR and 17O NMR methods showed that in an alkaline medium, one-electron reduction of iron(II) complex results in the formation of a stable pentacoordinated anionic complex.


Iron Physical Chemistry 2H2O Inorganic Chemistry Spectral Property 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Gregory, P., J. Porphyrins Phthalocyanines, 2000, vol. 4, no.4, p. 377.Google Scholar
  2. 2.
    The Phthalocyanines. Properties and Applications, vols. 1–4, Leznoff, C.C. and Lever, A.B.P., Eds., New York: VCH Publishers, 1989.Google Scholar
  3. 3.
    De la Torre, G., Vazques, P., Adullo-Lopez, F., and Torres, T., J. Mater. Chem., 1998, vol. 8, no.8, p. 1671.Google Scholar
  4. 4.
    Tarasevich, M.S. and Radyushkina, K.A., Kataliz i elektrokataliz metalloporfirinami (Catalysis and Electrocatalysis with Metal Porphyrins), Moscow: Nauka, 1982.Google Scholar
  5. 5.
    Kudrik, E.V., Makarov, S.V., Zahl, A., and Eldik van, R., Inorg. Chem., 2003, vol. 42, no.2, p. 618.Google Scholar
  6. 6.
    Porfiriny: Spektroskopiya, elektrokhimiya, primenenie (Porfirins: Spektroskopy, Elektrochemistry, Applications) Askarov, K.A., Berezin, B.D., Bystritska, E.V., et al., Eds., Moscow: Nauka, 1987.Google Scholar
  7. 7.
    Ferraudi, G., Inorg. Chem., 1979, vol. 18, no.4, p. 1005.Google Scholar
  8. 8.
    Gunter, M.S. and Turner, P., Coord. Chem. Rev., 1991, vol. 108, no.1, p. 115.Google Scholar
  9. 9.
    Stuzhin, P.A., Hamdush, M., and Zeiner, U., Inorg. Chim. Acta, 1995, vol. 236, nos.1–2, p. 131.Google Scholar
  10. 10.
    Bauer, E.M., Ercolani, C., Galh, P., et al., J. Porphyrins Phthalocyanines, 1999, vol. 3, no.3, p. 371.Google Scholar
  11. 11.
    Liao, M.S. and Scheiner, S., J. Chem. Phys., 2001, vol. 114, no.22, p. 9780.Google Scholar
  12. 12.
    Yu, B.-S. and Goff, H.M., J. Am. Chem. Soc., 1989, vol. 111, no.17, p. 6558.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2005

Authors and Affiliations

  • E. V. Kudrik
    • 1
  • V. N. Shishkin
    • 1
  • G. P. Shaposhnikov
    • 1
  1. 1.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

Personalised recommendations