Skip to main content
SpringerLink
Log in

Potassium, calcium, and strontium complexes with diphenyloxo-18-crown-6. Synthesis and vibrational spectra

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

New K, Ca, and Sr complexes with diphenyloxo-18-crown-6 (2,3,5,6-dibenzo-1,4,7,10,13,16-hexaoxocyclooctadecadiene-2,5, DPO18C6) were prepared and isolated as solids. Their IR spectra (400–4000 cm–1) were studied. On the basis of spectroscopic data, a structure was proposed for these compounds. In the complexes, DPO18C6 occurs in the inner sphere of K, Ca, and Sr. Only five oxygen atoms of the crown ether are involved in coordination, and the macrocycle conformation does not depend on the nature of the metal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Hiraoka, M., Crown Compounds: Properties and Applications, Tokyo: Kodansha, 1982.

    Google Scholar 

  2. Zolotov, Yu.A., Formanovskii, A.A., Pletnev, I.V., et al., Makrotsiklicheskie soedineniya v analiticheskoi khimii (Macrocyclic Compounds in Analytical Chemistry), Moscow: Nauka, 1993.

    Google Scholar 

  3. Lehn, J.-M. Supramolecular Chemistry. Concepts and Perspectives, VCH, 1995.

  4. Tsivadze, A. Yu., Varnek, A.A., and Khutorskii, V.E., Koordinatsionnye soedineniya metallov s kraun-ligandami (Coordination Compounds of Metals with Crown Ligands), Moscow: Nauka, 1991.

    Google Scholar 

  5. Bright, D. and Truter, M.R., J. Chem. Soc., B, 1970, no. 8, p. 1544.

  6. Dunitz, J.D. and Seiler, P., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1974, vol. 30, no. 11, p. 2739.

    Google Scholar 

  7. Kireeva, I.K., Generalova, N.B., Trofimov, V.A., and Tsivadze, A.Yu., Zh. Neorg. Khim., 1991, vol. 36, no. 6, p. 1464.

    Google Scholar 

  8. Raevskii, O.A., Tkachev, V.V., Atovmyan, L.O., et al., Koord. Khim., 1988, vol. 14, no. 12, p. 1697.

    Google Scholar 

  9. Kireeva, I.K., Trofimov, V.A., Generalova, N.B., and Tsivadze, A.Yu., Koord. Khim., 1989, vol. 15, no. 4, p. 463.

    Google Scholar 

  10. Tsivadze, A. Yu., Generalova, N.B., Pyatova, E.N., et al., Zh. Neorg. Khim., 1988, vol. 33, no. 7, p. 1649.

    Google Scholar 

  11. Nakomoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1986.

    Google Scholar 

  12. Raevskii, O.A., Yarkov, V.V., Zubareva, V.E., et al., Zh. Obshch. Khim., 1984, vol. 54, no. 12, p. 2760.

    Google Scholar 

  13. Parson, D.G., Truter, M.R., and Wingfield, J.N., Inorg. Chim. Acta, 1975, vol. 14, no. 1, p. 45.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia

    I. S. Ivanova, A. V. Dorokhov, I. K. Kireeva, E. N. Pyatova & A. Yu. Tsivadze

  2. All-Russia Research Institute of Chemical Technology, Kashirskoe sh. 33, 115230, Moscow, Russia

    V. V. Yakshin

Authors
  1. I. S. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Dorokhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. K. Kireeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. N. Pyatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Yakshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Yu. Tsivadze
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 2, 2005, pp. 98–103.

Original Russian Text Copyright © 2005 by Ivanova, Dorokhov, Kireeva, Pyatova, Yakshin, Tsivadze.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ivanova, I.S., Dorokhov, A.V., Kireeva, I.K. et al. Potassium, calcium, and strontium complexes with diphenyloxo-18-crown-6. Synthesis and vibrational spectra. Russ J Coord Chem 31, 90–94 (2005). https://doi.org/10.1007/s11173-005-0024-3

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11173-005-0024-3

Keywords

Search

Navigation