Synthesis of (η6-arene)tricarbonylchromium derivatives of 1,4-dihydro-3,1-benzoxazines

Abstract

A series of (η6-arene)tricarbonylchromium derivatives of 1,4-dihydro-3,1-benzoxazines was synthesized and characterized. The compounds were obtained by two alternative methods, namely, by the reaction of triammine(tricarbonyl)chromium with 1,4-dihydro-3,1-benzoxazines (method A) and by the condensation of (η6-2-aminobenzyl alcohol)tricarbonylchromium with various aldehydes and ketones (method B). The composition and structure of obtained compounds were established by different physicochemical methods of analysis, such as HPLC, UV, IR, 1H NMR spectroscopy, mass spectrometry, and X-ray diffraction.

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Correspondence to N. Yu. Grishina.

Additional information

The authors are grateful to the staff of the Chemical Department of the Lobachevsky State University of Nizhny Novgorod T. I. Liogon’kaya for the registration of IR spectra and Yu. B. Malysheva for the registration of 1H NMR spectra.

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 0729-2020-0039) in the framework of the Basic part of the Russian state assignment.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 171–178, January, 2021.

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Sazonova, E.V., Artemov, A.N., Faerman, V.I. et al. Synthesis of (η6-arene)tricarbonylchromium derivatives of 1,4-dihydro-3,1-benzoxazines. Russ Chem Bull 70, 171–178 (2021). https://doi.org/10.1007/s11172-021-3073-y

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Key words

  • 6-arene)tricarbonylchromium
  • 1,4-dihydro-3,1-benzoxazines
  • heterocyclic compounds
  • triammine(tricarbonyl)chromium