Skip to main content
SpringerLink
Log in

A new approach to the study of the structure of polyisoprene obtained by cationic polymerization

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The use of the T2 filter in NMR studies allowed us to separate carbon atoms by their mobility in different fragments of the macromolecular chain of polyisoprene synthesized by cationic polymerization. The NMR signals of terminal units with conjugated double bonds were identified for the first time for the “cationic” polyisoprene, which experimentally confirmed the transfer of the growing chain to the monomer in the process of cationic polymerization of isoprene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Z. Li, W. Ren, H. Chen, L. Ye, Y. Zhang, Polym. Int., 2012, 61, 531.

    Article  CAS  Google Scholar 

  2. V. A. Rozentsvet, V. G. Kozlov, E. F. Ziganshina, N. P. Boreiko, S. V. Kostjuk, Polym. Int., 2013, 62, 817.

    Article  CAS  Google Scholar 

  3. V. A. Rozentsvet, V. G. Kozlov, E. F. Ziganshina, N. P. Boreiko, A. S. Khachaturov, Russ. J. Appl. Chem., 2009, 82, 148.

    Article  CAS  Google Scholar 

  4. V. A. Rozentsvet, Tez. dokl. V Mezhdunar. konf. po khimii i fiziko-khimii oligomerov [Abstrs Internat. Conf. on Chemistry and Physical Chemistry of Oligomers] (Volgograd, June 1–6, 2015), VolgGTU, 2015. v. 1, p. 18 (in Russian).

    Google Scholar 

  5. V. A. Rozentsvet, V. G. Kozlov, Yu. B. Monakov, Kationnaya polimerizatsiya sopryazhennykh diyenov [Cationic Poly merization of Conjugated Dienes], Nauka, Moscow, 2011, 238 pp. (in Russian).

    Google Scholar 

  6. J. P. Kennedy, Cationic Polymerization of Olefins: A Critical Inventory, Wiley-Interscience, New-York, 1975, 407 pp.

    Google Scholar 

  7. S. Ouardad, A. Defleux, F. Peruch, Pure Appl. Chem., 2012, 84, 2065.

    Article  CAS  Google Scholar 

  8. J. E. Puskas, F. Peruch, A. Defleux, D. E. Dabney, C. Wesdemiotis, H. Li, A. Lindsay, J. Polym. Sci., Part A: Polym. Chem., 2009, 47, 2172.

    Article  CAS  Google Scholar 

  9. S. V. Kostjuk, S. Ouardad, F. Peruch, A. Defleux, C. Absalon, J. E. Puskas, F. Ganachaud, Macromolecules, 2011, 44, 1372.

    Article  CAS  Google Scholar 

  10. V. A. Rozentsvet, V. G. Kozlov, E. F. Ziganshina, N. P. Boreiko, Polym. Sci., Ser. A, 2008, 50, 1038.

    Article  Google Scholar 

  11. V. A. Rozentsvet, A. S. Khachaturov, V. P. Ivanova, Polym. Sci., Ser. A, 2009, 51, 870.

    Article  Google Scholar 

  12. V. A. Rozentsvet, V. G. Kozlov, N. A. Korovina, O. A. Stotskaya, O. I. Gnezdilov, S. V. Kostjuk, Macromol. Chem. Phys., 2016, 217, 1860.

    Article  CAS  Google Scholar 

  13. V. A. Rozentsvet, V. G. Kozlov, N. A. Sablina, O. A. Stotskaya, F. Peruch, S. V. Kostjuk, Polym. Chem., 2017, 8, 926.

    Article  CAS  Google Scholar 

  14. V. A. Rozentsvet, N. A. Korovina, O. A. Stotskaya, M. G. Kuznetsova, F. Peruch, S. V. Kostjuk, J. Polym. Sci., Part A: Polym. Chem., 2016, 54, 2430.

    Article  CAS  Google Scholar 

  15. V. A. Rozentsvet, V. G. Kozlov, O. A. Stotskaya, N. A. Sablina, F. Peruch, S. V. Kostjuk, Eur. Polym. J., 2018, 103, 11.

    Article  CAS  Google Scholar 

  16. L. P. Lindeman, J. Q. Adams, Anal. Chem., 1971, 43, 1245.

    Article  CAS  Google Scholar 

  17. V. A. Rozentsvet, V. G. Kozlov, E. F. Ziganshina, N. P. Boreiko, Int. J. Polym. Anal. Charact., 2009, 14, 631.

    Article  CAS  Google Scholar 

  18. T. T. Denisova, I. A. Livshits, E. R. Gershtein, Polym. Sci., Ser. A, 1974, 16, 1017.

    Google Scholar 

  19. C. Vautrin-Ul, F. Pla, A. Petit, Makromol. Chem.: Macromol. Symp., 1997, 119, 197.

    CAS  Google Scholar 

  20. T. D. W. Claridge, High-Resolution NMR Techniques in Organic Chemistry, Elsevier Science, Amsterdam, 1999, 382 pp.

    Google Scholar 

  21. H. Matsushita, E. Negishi, J. Org. Chem., 1982, 47, 4161.

    Article  CAS  Google Scholar 

  22. A. S. Khachaturov, V. P. Ivanova, Russ. J. Gen. Chem., 1984, 54, 1341.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Ecology of the Volga River Basin, Russian Academy of Sciences, 10 ul. Komzina, 445003, Togliatti, Russian Federation

    V. A. Rozentsvet, V. G. Kozlov & O. A. Stotskaya

  2. St.-Petersburg State University, Department of Chemistry, 7–9 Universitetskaya nab., 199034, St.-Petersburg, Russian Federation

    S. N. Smirnov & P. M. Tolstoy

Authors
  1. V. A. Rozentsvet
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Kozlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. A. Stotskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. N. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. M. Tolstoy
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Rozentsvet.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0116–0120, January, 2019.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rozentsvet, V.A., Kozlov, V.G., Stotskaya, O.A. et al. A new approach to the study of the structure of polyisoprene obtained by cationic polymerization. Russ Chem Bull 68, 116–120 (2019). https://doi.org/10.1007/s11172-019-2425-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-019-2425-3

Key words

Search

Navigation