Mixed micellar systems of metal complexes of alkylated N-methyl-d-glucamines with hexadecyltrimethylammonium bromide

Abstract

The spectral, aggregation, and adsorption properties of amphiphilic metal complexes of alkylated N-methyl-D-glucamines and lanthanum nitrate and their mixture with hexadecyltrimethylammonium bromide were studied using IR, UV, and 1H NMR spectroscopy, tensiometry, potentiometry, and dynamic and electrophoretic light scattering. The parameters of aggregation and adsorption at the interface were determined and compared with the parameters of the ligands, ligand–inorganic salt mixtures, and traditional cationic surfactants.

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Correspondence to E. P. Zhil´tsova.

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Dedicated to Academician of the Russian Academy of Sciences A. I. Konovalov on the occasion of his 85th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0424–0430, February, 2019.

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Ibatullina, M.R., Zhil´tsova, E.P., Lukashenko, S.S. et al. Mixed micellar systems of metal complexes of alkylated N-methyl-d-glucamines with hexadecyltrimethylammonium bromide. Russ Chem Bull 68, 424–430 (2019). https://doi.org/10.1007/s11172-019-2403-9

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Key words

  • alkylated N-methyl-d-glucamine
  • metallocomplex
  • surfactant
  • aggregation
  • adsorption