NMR study of the Ni complexes based on 1-alkyl-1,2-diphospholes

Abstract

The structures of the nickel complexes based on 1-alkyl-1,2-diphospholes in a solution were determined using 1D/2D homo- and heterocorrelation NMR experiments. The η2 coordination mode at the P–P bond is observed in the complexes.

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Correspondence to Sh. K. Latypov.

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Dedicated to Academician of the Russian Academy of Sciences A. I. Konovalov on the occasion of his 85th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0374–0379, February, 2019.

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Kondrashova, S.A., Ganushevich, Y.S., Kharlamov, S.V. et al. NMR study of the Ni complexes based on 1-alkyl-1,2-diphospholes. Russ Chem Bull 68, 374–379 (2019). https://doi.org/10.1007/s11172-019-2395-5

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Key words

  • heterocorrelation NMR spectroscopy
  • coordination
  • phosphorus-containing ligands
  • nickel complexes