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Influence of the composition on the electrochemical properties of cathode materials xLi2MnO3•(1–x)LiMn1/3Ni1/3Co1/3O2 for lithium-ion batteries

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Abstract

Lithium-rich transition metal complex oxides of the general composition xLi2MnO3• •(1–x)LiMO2 (M = MnaNibCoc, a + b + c = 1) were synthesized by coprecipitation and modified Pechini method. The influence of the oxide phase composition on their electrochemical performance as cathode materials was studied in lithium half-cells. Effects of the synthetic approach and synthesis conditions on the morphology and electrochemical characteristics of the materials obtained were considered. The composition 0.35Li2MnO3• •0.65LiMn1/3Ni1/3Co1/3O2 demonstrates the highest discharge capacity retention during cycling. The samples with discharge capacity of 290 mA h g–1 were obtained.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    L. S. Pechen, E. V. Makhonina, V. V. Volkov, V. S. Pervov & I. L. Eremenko

  2. A. F. Ioffe Physico-Technical Institute, Russian Academy of Sciences, 26 ul. Politechnicheskaya, 194021, St. Petersburg, Russian Federation

    A. M. Rumyantsev & Yu. M. Koshtyal

  3. Peter the Great St. Petersburg Polytechnic University, 29 ul. Politechnicheskaya, 195251, St. Petersburg, Russian Federation

    A. M. Rumyantsev & Yu. M. Koshtyal

  4. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119334, Moscow, Russian Federation

    A. S. Goloveshkin

Authors
  1. L. S. Pechen
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  2. E. V. Makhonina
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  3. A. M. Rumyantsev
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  4. Yu. M. Koshtyal
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  5. V. V. Volkov
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  6. A. S. Goloveshkin
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  7. V. S. Pervov
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  8. I. L. Eremenko
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Correspondence to L. S. Pechen.

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Dedicated to Academician of the Russian Academy of Sciences A. I. Konovalov on the occasion of his 85th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0293–0300, February, 2019.

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Pechen, L.S., Makhonina, E.V., Rumyantsev, A.M. et al. Influence of the composition on the electrochemical properties of cathode materials xLi2MnO3•(1–x)LiMn1/3Ni1/3Co1/3O2 for lithium-ion batteries. Russ Chem Bull 68, 293–300 (2019). https://doi.org/10.1007/s11172-019-2385-7

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  • DOI: https://doi.org/10.1007/s11172-019-2385-7

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