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Russian Chemical Bulletin

, Volume 67, Issue 12, pp 2259–2261 | Cite as

Complexation of a crown-substituted naphthalimide derivative with heavy metals in Langmuir monolayers

  • I. I. Shepeleva
  • A. V. Shokurov
  • L. B. Bogdanova
  • V. V. Arslanov
  • P. A. Panchenko
  • O. A. Fedorova
  • S. L. SelektorEmail author
Full Articles
  • 16 Downloads

Abstract

It was demonstrated that, in contrast to a solution in an organic solvent, the relaxation of the excited state of a fluorophore moiety proceeds mainly radiationless upon the formation of naphthalimide fluoroionophore complexes with complementary cations in a monolayer on a water surface. Apparently, this is due to the fact that the distribution of the energy levels of molecular orbitals in the fluoroionophore complexes with cations at the air-water interfaces changes in such a way that relaxation of the excited state via charge transfer within the complex molecule remains possible.

Key words

naphthalimides crown ethers Langmuir monolayers fluorescence complexation 

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • I. I. Shepeleva
    • 1
    • 2
  • A. V. Shokurov
    • 1
  • L. B. Bogdanova
    • 1
  • V. V. Arslanov
    • 1
  • P. A. Panchenko
    • 3
  • O. A. Fedorova
    • 3
  • S. L. Selektor
    • 1
    Email author
  1. 1.A. N. Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Russian Technological University, M. V. Lomonosov Moscow State University of Fine Chemical TechnologiesMoscowRussian Federation
  3. 3.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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