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Supramolecular structuring of aqueous solutions of strong acids: manifestations in light scattering, NMR, and oxidation kinetics. Does liquid have a drop-like nature?

2. Perchloric acid

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Abstract

The properties of large (~100 nm) aggregates, that is, solvate associates formed in aqueous solutions of perchloric acid, including their stability in time, dependence of their structure on the solution composition and preparation procedure, and effects of temperature and mechanical impacts were studied by light scattering methods. The slow supramolecular structuring in aqueous solutions of perchloric acid was compared with the previously studied structuring in aqueous solutions of nitric acid. A number of regularities and features that can significantly affect the chemical processes in these solutions were revealed.

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References

  1. G. V. Lagodzinskaya, T. V. Laptinskaya, A. I. Kazakov, Russ. Chem. Bull, 2018, 67, 1838.

    Article  CAS  Google Scholar 

  2. Yu. I. Rubtsov, A. I. Kazakov, T. V. Sorokina, G. B. Manelis, Russ. Chem. Bull., 2008, 57, 2065; DOI: 10.1007/s11172-008-0280-8.

    Article  CAS  Google Scholar 

  3. G. B. Manelis, G. V. Lagodzinskaya, A. I. Kazakov, A. V. Chernyak, N. G. Yunda, L. S. Kurochkina, Russ. Chem. Bull., 2013, 62, 994; DOI: 10.1007/s11172-013-0130-1.

    Article  CAS  Google Scholar 

  4. G. V. Lagodzinskaya, N. G. Yunda, G. B. Manelis, Russ. Chem. Bull., 2006, 55, 597; DOI: 10.1007/s11172-006-0302-3.

    Article  CAS  Google Scholar 

  5. G. V. Lagodzinskaya, T. V. Laptinskaya, A. I. Kazakov, L. S. Kurochkina, G. B. Manelis, Russ. Chem. Bull., 2016, 65, 984; DOI: 10.1007/s11172-016-1401-4.

    Article  CAS  Google Scholar 

  6. G. Cainelli, P. Galletti, D. Giacomini, Chem. Soc. Rev. 2009, 38, 990.

    Article  CAS  PubMed  Google Scholar 

  7. L. O. Kononov, RSC Adv., 2015, 5, 46718.

    Article  CAS  Google Scholar 

  8. M. Sedlak, J. Phys. Chem. B, 2006, 110, 4329.

    Article  CAS  PubMed  Google Scholar 

  9. M. Sedlak, J. Phys. Chem. B, 2006, 110, 4339.

    Article  CAS  PubMed  Google Scholar 

  10. M. Sedlak, J. Phys. Chem. B, 2006, 110, 13976.

    Article  CAS  PubMed  Google Scholar 

  11. Photon Correlation and Light Beating Spectroscopy, Eds H. Z. Cummins, E. R. Pike, Plenum Press, New York-London, 1974.

  12. P. G. De Gennes, Scaling Concepts in Polymer Physics, Cornell Univ. Press, Ithaca-London, 1979, 324 pp.

    Google Scholar 

  13. Dynamic Light Scattering. The Method and Some Applications, Ed. W. Brown, Clarendon Press-New York-Oxford University Press, Oxford, 1993, 752.

  14. M. N. Kirichenko, A. T. Sanoeva, L. L. Chaikov, Bull. Lebedev Phys. Institute, 2016, 43, 256.

    Article  Google Scholar 

  15. O. V. Vyshivannaya, T. V. Laptinskaya, Polym. Sci., Ser. A, 2012, 54, 364.

    Article  CAS  Google Scholar 

  16. G. V. Lagodzinskaia, I. Yu. Kozyreva, N. G. Yunda, G. B. Manelis, Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1984, 33, 2017.

    Article  Google Scholar 

  17. A. I. Kitaigorodskii, Molecular Crystals and Molecules, Academic Press, London, 1973, 553 pp.

    Google Scholar 

  18. J.-M. Lehn, Rep. Prog. Phys., 2004, 67, 249.

    Article  Google Scholar 

  19. R. Roy, W. A. Tiller, I. Bell, M. R. Hoover, Mater. Res. Innov., 2005, 9, 577.

    Article  CAS  Google Scholar 

  20. D. P. Shelton, J. Chem. Phys., 2014, 141, 224506.

    Article  CAS  PubMed  Google Scholar 

  21. M. H. Rausch, J. Lehmann, A. Leipertz, A. P. Froba, Phys. Chem. Chem. Phys., 2011, 13, 9525.

    Article  CAS  PubMed  Google Scholar 

  22. A. V. Anikeenko, G. G. Malenkov, Yu. I. Naberukhin, J. Struct. Chem. (Engl. Transl.), 2016, 57, 1660.

    Article  CAS  Google Scholar 

  23. A. V. Anikeenko, G. G. Malenkov, Yu. I. Naberukhin, Dokl. Phys. Chem. (Engl. Transl.), 2017, 472, 16.

    Article  CAS  Google Scholar 

  24. A. V. Anikeenko, G. G. Malenkov, Y. I. Naberukhin, J. Chem. Phys., 2018, 148, 094508; DOI: 10.1063/1.5018140.

    Article  CAS  Google Scholar 

  25. A. V. Orlova, D. E. Tsvetkov, L. O. Kononov, Russ. Chem. Bull., 2017, 66, 1712.

    Article  CAS  Google Scholar 

  26. A. V. Orlova, T. V. Laptinskaya, N. V. Bovin, L. O. Kononov, Russ. Chem. Bull., 2017, 66, 2173.

    Article  CAS  Google Scholar 

  27. S. Krickl, T. Buchecker, A. U. Meyer, I. Grillo, D. Touraud, P. Bauduin, B. Konig, A. Pfitzner, W. Kunz, Phys. Chem. Chem. Phys., 2017, 19, 23773; DOI:10.1039/C7CP02134H.

    Article  CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    G. V. Lagodzinskaya & A. I. Kazakov

  2. Department of Physics, M. V. Lomonosov Moscow State University, Build. 2, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    T. V. Laptinskaya

Authors
  1. G. V. Lagodzinskaya
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  2. T. V. Laptinskaya
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  3. A. I. Kazakov
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Correspondence to G. V. Lagodzinskaya.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2212–2223, December, 2018.

For Part 1, see Ref. 1.

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Lagodzinskaya, G.V., Laptinskaya, T.V. & Kazakov, A.I. Supramolecular structuring of aqueous solutions of strong acids: manifestations in light scattering, NMR, and oxidation kinetics. Does liquid have a drop-like nature?. Russ Chem Bull 67, 2212–2223 (2018). https://doi.org/10.1007/s11172-018-2358-2

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  • DOI: https://doi.org/10.1007/s11172-018-2358-2

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