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Supramolecular organization of crown- and phosphoryl-containing magnesium and zinc phthalocyaninates in solutions of synthetic and natural surfactants

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Abstract

The behavior of crown- and phosphoryl-containing magnesium and zinc phthalocyaninates in solutions of synthetic and natural surfactants is studied. In a phosphate buffer (рН 7.4), zinc phthalocyaninate bearing oxy(pentyloxy)phosphoryl groups in peripheral substituents of the macrocycle is in aggregated state. According to absorption and fluorescence spectroscopy data, adding oppositely charged synthetic and natural surfactants leads to monomerization of this compound. The degree of monomerization of magnesium octa[(4´-benzo-15-crown-5)oxy]-phthalocyaninate in a microheterogeneous medium is affected by the concentration of sodium cholate and ionic strength. Fluorescence-active supramolecular gels based on sodium deoxycholate were prepared using phosphoryl-containing zinc phthalocyaninate.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    N. F. Goldshleger, V. Yu. Gak & M. A. Lapshina

  2. Moscow Region State University, 10А ul. Radio, 105005, Moscow, Russian Federation

    M. A. Lapshina

  3. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Building 4, 31 Leninsky prosp., 119071, Moscow, Russian Federation

    V. E. Baulin, A. A. Shiryaev & A. Yu. Tsivadze

  4. Institute of Physiologically Active Compounds, Russian Academy of Sciences, 1 Severnyj proezd, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. E. Baulin

Authors
  1. N. F. Goldshleger
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  2. V. Yu. Gak
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  3. M. A. Lapshina
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  4. V. E. Baulin
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  5. A. A. Shiryaev
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  6. A. Yu. Tsivadze
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Corresponding authors

Correspondence to N. F. Goldshleger or V. E. Baulin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2205–2211, December, 2018.

Based on the materials of the VII International Conference on Physical Chemistry of Crown Compounds, Porphyrins, and Phthalocyanines (September 9–14, 2018, Tuapse, Russia).

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Goldshleger, N.F., Gak, V.Y., Lapshina, M.A. et al. Supramolecular organization of crown- and phosphoryl-containing magnesium and zinc phthalocyaninates in solutions of synthetic and natural surfactants. Russ Chem Bull 67, 2205–2211 (2018). https://doi.org/10.1007/s11172-018-2357-3

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  • DOI: https://doi.org/10.1007/s11172-018-2357-3

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