Russian Chemical Bulletin

, Volume 67, Issue 12, pp 2201–2204 | Cite as

Synthesis and spectral luminescent properties of 4,4´,4´´,4´´´-tetra(tert-butyl)-5,5´,5´´,5´´´-tetrakis(phenylsulfanyl)phthalocyanines and their sulfo acids

  • T. V. TikhomirovaEmail author
  • S. A. Znoyko
  • A. I. Petlina
  • A. A. Filippova
  • V. E. Maizlish
  • A. S. Vashurin
Full Articles


Magnesium and zinc complexes of 4,4´,4´´,4´´´-tetra(tert-butyl)-5,5´,5´´,5´´´-tetra kis-(phenylsulfanyl)phthalocyanine were synthesized. The corresponding sulfo acids were prepared by sulfochlorination and further hydrolysis. Spectral luminescent properties of the synthesized phthalocyanine derivatives were studied. Introduction of sulfo groups resulted in a bathochromic shift of Q-band in the spectra recorded in DMF and pyridine regardless of the metal nature as well as in a hypsochromic shift in sulfuric acid.

Key words

phthalocyanines metal complexes sulfo acids luminescence 


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  1. 1.
    Y. G. Gorbunova, A. Martynov, P. Stuzhin, O. I. Koifman, Macroheterocycles, 2017, 10, 400.CrossRefGoogle Scholar
  2. 2.
    A. Ishikawa, K. Ohta, M. Yasutake, J. Porphyrins Phthalocyanines, 2015, 19, 1.CrossRefGoogle Scholar
  3. 3.
    S. S. Smola, O. V. Snurnikova, E. N. Fadeyev, A. A. Sinelshchikova, Y. G. Gorbunova, L. A. Lapkina, A. Yu. Tsivadze, N. V. Rusakova, Macroheterocycles, 2012, 5, 343.CrossRefGoogle Scholar
  4. 4.
    K. Sakamoto, S. Yoshino, M. Takemoto, K. Sugaya, H. Kubo, T. Komoriya, Sh. Kamei, Sh. Furukawa, Am. J. Anal. Chem., 2014, 92, 1037.CrossRefGoogle Scholar
  5. 5.
    K. I. Sakamoto, E. Ohno-Okumura, Materials, 2009, 2, 1127.CrossRefGoogle Scholar
  6. 6.
    O. M. Bankole, T. Nyokong, J. Coord. Chem., 2015, 68, 3727.CrossRefGoogle Scholar
  7. 7.
    J. Wei, X. Li, Ch. Xiao, F. Lu, Vibrational Spectroscopy, 2017, 92, 105.CrossRefGoogle Scholar
  8. 8.
    K. A. Volkov, G. V. Avramenko, V. M. Negrimovskii, E. A. Luk´yanets, Russ. J. Gen. Chem., 2007, 77, 1108.CrossRefGoogle Scholar
  9. 9.
    V. I. Makarov, S. Yu. Vasil´chenko, A. V. Ryabova, V. I. Konov, E. N. Shevchenko, E. A. Lukyanets, A. E. Ermakov, V. B. Loschenov, Russ. J. Gen. Chem., 2015, 85, 338.CrossRefGoogle Scholar
  10. 10.
    V. M. Negrimovsky, E. A. Makarova, S. A. Mikhalenko, L. I. Solov´eva, O. A. Yuzhakova, V. F. Donyagina, K. A. Volkov, A. N. Komissarov, E. N. Shevchenko, S. V. Dudkin, A. P. Berezina, A. P. Lastovoy, E. A. Lukyanets, Russ. J. Gen. Chem., 2015, 85, 240.CrossRefGoogle Scholar
  11. 11.
    A. S. Vashurin, Russ. Chem. Bull., 2016, 65, 2220.CrossRefGoogle Scholar
  12. 12.
    A. Weissberger, E. S. Proskauer, J. A. Riddick, E. E. Toops, Organic Solvents: Physical Properties and Methods of Puri fication, Inter. Science Publishers Inc., New York, 1955, 520 pp.Google Scholar
  13. 13.
    A. Vashurin, V. Maizlish, T. Tikhomirova, M. Nemtseva, S. Znoyko, V. Aleksandriiskii, J. Mol. Struct., 2018, 1160, 440.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • T. V. Tikhomirova
    • 1
    Email author
  • S. A. Znoyko
    • 1
  • A. I. Petlina
    • 1
  • A. A. Filippova
    • 1
  • V. E. Maizlish
    • 1
  • A. S. Vashurin
    • 1
  1. 1.Ivanovo State University of Chemical TechnologyIvanovoRussian Federation

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