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Russian Chemical Bulletin

, Volume 67, Issue 12, pp 2201–2204 | Cite as

Synthesis and spectral luminescent properties of 4,4´,4´´,4´´´-tetra(tert-butyl)-5,5´,5´´,5´´´-tetrakis(phenylsulfanyl)phthalocyanines and their sulfo acids

  • T. V. TikhomirovaEmail author
  • S. A. Znoyko
  • A. I. Petlina
  • A. A. Filippova
  • V. E. Maizlish
  • A. S. Vashurin
Full Articles
  • 18 Downloads

Abstract

Magnesium and zinc complexes of 4,4´,4´´,4´´´-tetra(tert-butyl)-5,5´,5´´,5´´´-tetra kis-(phenylsulfanyl)phthalocyanine were synthesized. The corresponding sulfo acids were prepared by sulfochlorination and further hydrolysis. Spectral luminescent properties of the synthesized phthalocyanine derivatives were studied. Introduction of sulfo groups resulted in a bathochromic shift of Q-band in the spectra recorded in DMF and pyridine regardless of the metal nature as well as in a hypsochromic shift in sulfuric acid.

Key words

phthalocyanines metal complexes sulfo acids luminescence 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • T. V. Tikhomirova
    • 1
    Email author
  • S. A. Znoyko
    • 1
  • A. I. Petlina
    • 1
  • A. A. Filippova
    • 1
  • V. E. Maizlish
    • 1
  • A. S. Vashurin
    • 1
  1. 1.Ivanovo State University of Chemical TechnologyIvanovoRussian Federation

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