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Russian Chemical Bulletin

, Volume 67, Issue 12, pp 2195–2200 | Cite as

Spectrophotometric study of the cation-induced dimerization of heteroleptic terbium(III) tetra-15-crown-5-bisphthalocyaninate

  • A. G. MartynovEmail author
  • A. V. Bykov
  • Yu. G. Gorbunova
  • A. Yu. Tsivadze
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  • 26 Downloads

Abstract

We proposed a new approach to the synthesis of heteroleptic crown-substituted terbium(III) bisphthalocyaninate, [(15C5)4Pc]Tb(Pc) (1) based on the reaction of unsubstituted lanthanum bisphthalocyaninate (La(Pc)2) with tetra-15-crown-5-phthalocyanine (H2[(15C5)4Pc]) and terbium(III) acetate in a mixture of octanol and chloronaphthalene in the presence of 1,8-diazabicyclo[ 5.4.0]undec-7-ene as an organic base. For the first time, we carried out a comparative spectrophotometric titration of compound 1 with MBPh4 solutions (M = K, Rb, Cs) and demonstrated the formation of isostructural cofacial supramolecular dimers. Spectral-structural correlations were developed for evaluation of the distances between phthalocyanine ligands in new supramolecular assemblies, which can be used for the development of polynuclear suprasingle-molecule magnetic materials.

Key words

spectrophotometry terbium(III) tetra-15-crown-5-bisphthalocyaninate supramolecular assembly 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • A. G. Martynov
    • 1
    Email author
  • A. V. Bykov
    • 2
  • Yu. G. Gorbunova
    • 1
    • 3
  • A. Yu. Tsivadze
    • 1
    • 3
  1. 1.A. N. Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Department of ChemistryLomonosov Moscow State UniversityMoscowRussian Federation
  3. 3.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussian Federation

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