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Spectrophotometric study of the cation-induced dimerization of heteroleptic terbium(III) tetra-15-crown-5-bisphthalocyaninate

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Abstract

We proposed a new approach to the synthesis of heteroleptic crown-substituted terbium(III) bisphthalocyaninate, [(15C5)4Pc]Tb(Pc) (1) based on the reaction of unsubstituted lanthanum bisphthalocyaninate (La(Pc)2) with tetra-15-crown-5-phthalocyanine (H2[(15C5)4Pc]) and terbium(III) acetate in a mixture of octanol and chloronaphthalene in the presence of 1,8-diazabicyclo[ 5.4.0]undec-7-ene as an organic base. For the first time, we carried out a comparative spectrophotometric titration of compound 1 with MBPh4 solutions (M = K, Rb, Cs) and demonstrated the formation of isostructural cofacial supramolecular dimers. Spectral-structural correlations were developed for evaluation of the distances between phthalocyanine ligands in new supramolecular assemblies, which can be used for the development of polynuclear suprasingle-molecule magnetic materials.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Build. 4, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. G. Martynov, Yu. G. Gorbunova & A. Yu. Tsivadze

  2. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    A. V. Bykov

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    Yu. G. Gorbunova & A. Yu. Tsivadze

Authors
  1. A. G. Martynov
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  2. A. V. Bykov
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  3. Yu. G. Gorbunova
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  4. A. Yu. Tsivadze
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Correspondence to A. G. Martynov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2195–2200, December, 2018

Based on the materials of the VII International Conference on Physical Chemistry of Crown Compounds, Porphyrins, and Phthalocyanines (September 9–14, 2018, Tuapse, Russia).

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Martynov, A.G., Bykov, A.V., Gorbunova, Y.G. et al. Spectrophotometric study of the cation-induced dimerization of heteroleptic terbium(III) tetra-15-crown-5-bisphthalocyaninate. Russ Chem Bull 67, 2195–2200 (2018). https://doi.org/10.1007/s11172-018-2355-5

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  • DOI: https://doi.org/10.1007/s11172-018-2355-5

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