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Complexation of tetrafluoroboric acid with benzo-15-crown-5

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Abstract

The extraction of tetrafluoroboric acid from aqueous solutions to a solution of benzo-15-crown-5 (B15С5, 1 mol L-1) in chloroform is shown to occur due to complexation with the ratio of components HBF4: B15С5 = 1: 1.5. It was revealed by IR spectroscopy that the whole crown ether in the extract is coordinated. The 1: 1 HBF4•В15С5 complex was isolated and characterized using IR spectroscopy and X-ray diffraction analysis. The O(2) and O(4) atoms of the crown ether ring participate in the coordination.

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References

  1. K. G. Heumann, Top. Curr. Chem., 1985, 127, 77.

    Article  CAS  Google Scholar 

  2. A. A. Abramov, Moscow Univ. Chem. Bull., Ser. Khim., 2000, 41, 3.

    CAS  Google Scholar 

  3. V. V. Yakshin, N. A. Tsarenko, A. M. Koshcheev, I. G. Tananaev, B. F. Myasoedov, Sov. Radiochem., 2012, 54, 54.

    Article  CAS  Google Scholar 

  4. K. Nishizawa, Sh. Ishino, H. Watanabe, M. Shinagawa, J. Nuclear Science and Technology, 1984, 21, 694.

    Article  CAS  Google Scholar 

  5. K. Nishizawa, T. Takano, I. Ikeda & M. Okahara, Separation Science and Technology, 1988, 23, 333.

    Article  CAS  Google Scholar 

  6. L. I. Demina, L. G. Kuz´mina, S. V. Demin, N. A. Shokurova, V. I. Zhilov, A. Yu. Tsivadze, Russ. J. Inorg. Chem., 2017, 62, 1536.

    Article  CAS  Google Scholar 

  7. L. G. Kuz´mina, L. I. Demina, S. V. Demin, N. A. Shokurova, V. I. Zhilov, A. Yu. Tsivadze, Russ. J. Inorg. Chem., 2018, 63, 357.

    Article  Google Scholar 

  8. G. V. Kostikova, O. G. Krasnova, L. I. Demina, V. I. Zhilov, Zh. Neorg. Khim. [Russ. J. Inorg. Chem.], 2018, No. 11 (in Russian).

    Google Scholar 

  9. SAINT. Version 6.02A, Bruker AXS Inc. Madison, Wisconsin, USA, 2001.

  10. SHELXTL-Plus. Version 5.10, Bruker AXS Inc. Madison, Wisconsin, USA, 1997.

  11. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Crystallogr., 2009, 42, 339.

    Article  CAS  Google Scholar 

  12. N. A. Shokurova, L. I. Demina, V. I. Zhilov, S. V. Demin, A. Yu. Tsivadze, Russ. J. Inorg. Chem., 2016, 61, 787.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Build. 4, 31 Leninsky prosp., 199071, Moscow, Russian Federation

    V. I. Zhilov, G. V. Kostikova, L. I. Demina, S. V. Demin & A. Yu. Tsivadze

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    L. G. Kuz´mina

Authors
  1. V. I. Zhilov
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  2. G. V. Kostikova
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  3. L. G. Kuz´mina
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  4. L. I. Demina
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  5. S. V. Demin
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  6. A. Yu. Tsivadze
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Corresponding author

Correspondence to V. I. Zhilov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2191–2194, December, 2018.

Based on the materials of the VII International Conference on Physical Chemistry of Crown Compounds, Porphyrins, and Phthalocyanines (September 9–14, 2018, Tuapse, Russia).

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Zhilov, V.I., Kostikova, G.V., Kuz´mina, L.G. et al. Complexation of tetrafluoroboric acid with benzo-15-crown-5. Russ Chem Bull 67, 2191–2194 (2018). https://doi.org/10.1007/s11172-018-2354-6

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  • DOI: https://doi.org/10.1007/s11172-018-2354-6

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