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Synthesis of oligosiloxanes with 3-aminopropyl groups and their testing as surfactants in the preparation of polymer microspheres

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Abstract

Polydimethyl-co-methyl(3-aminopropyl)siloxanes differing in the content of amino groups and molecular weight were synthesized by two pathways, namely, by hydrosilylation of oligodimethyl-co-methylhydrоsiloxane with N-(trimethylsilyl)allylamine (TMSAA) and by copolymerization of octamethylcyclotetrasiloxane with methyl(3-aminopropyl)cyclosiloxanes. The colloid-chemical properties of the synthesized oligomers were studied. The oligosiloxanes possess high surface activity and can reduce the interfacial tension in the interface surfactant solution in toluene–water to 6.7–4.2 mJ m2. Aggregatively stable polystyrene suspensions with particle of 0.5 and 0.8 μm in diameter were obtained in the presence of the synthesized oligomers.

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Authors and Affiliations

  1. MIREA – Russian Technological University, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    I. A. Gritskova & A. A. Ezhova

  2. State Research Institute of Chemistry and Technology of Organoelement Compounds, 38 sh. Entuziastov, 111123, Moscow, Russian Federation

    V. G. Lakhtin, I. B. Sokolskaya, I. N. Krizhanovsky & P. A. Storozhenko

  3. N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    D. I. Shragin & A. M. Muzafarov

  4. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. I. Shragin & A. M. Muzafarov

Authors
  1. I. A. Gritskova
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  2. V. G. Lakhtin
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  3. D. I. Shragin
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  4. A. A. Ezhova
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  5. I. B. Sokolskaya
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  6. I. N. Krizhanovsky
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  7. P. A. Storozhenko
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  8. A. M. Muzafarov
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Corresponding author

Correspondence to A. A. Ezhova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1908–1914, October, 2018.

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Gritskova, I.A., Lakhtin, V.G., Shragin, D.I. et al. Synthesis of oligosiloxanes with 3-aminopropyl groups and their testing as surfactants in the preparation of polymer microspheres. Russ Chem Bull 67, 1908–1914 (2018). https://doi.org/10.1007/s11172-018-2306-1

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  • DOI: https://doi.org/10.1007/s11172-018-2306-1

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