Abstract
Adsorption of methane on three samples of metal-organic framework structures (MOF), which contain copper, aluminum or zinc atoms, was measured at temperatures ranging from 303 to 333 K and pressures up to 40 MPa using a precise volumetric-gravimetric unit. The determined values of adsorption volumes and characteristic energies served to evaluate the average heats of adsorption, which were compared to the average isosteric heats of adsorption.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1807–1813, October, 2018.
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Pribylov, A.A., Murdmaa, K.O., Solovtsova, O.V. et al. Methane adsorption on various metal-organic frameworks and determination of the average adsorption heats at supercritical temperatures and pressures. Russ Chem Bull 67, 1807–1813 (2018). https://doi.org/10.1007/s11172-018-2293-2
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DOI: https://doi.org/10.1007/s11172-018-2293-2