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A new method for the preparation of 1-(chloromethyl)- and 1-(dichloromethyl)silatranes

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Abstract

A preparative method for the synthesis of 1-(chloromethyl)- and 1-(dichloromethyl)silatranes was developed based on the reactions of 1-chlorosilatrane with the binary P(NMe2)3–СHX3 system (X3 = HBrCl, Cl3).

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    N. F. Lazareva & I. M. Lazarev

Authors
  1. N. F. Lazareva
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  2. I. M. Lazarev
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Correspondence to N. F. Lazareva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1742–1743, September, 2018.

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Lazareva, N.F., Lazarev, I.M. A new method for the preparation of 1-(chloromethyl)- and 1-(dichloromethyl)silatranes. Russ Chem Bull 67, 1742–1743 (2018). https://doi.org/10.1007/s11172-018-2285-2

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  • DOI: https://doi.org/10.1007/s11172-018-2285-2

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