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Structural-dimensional effects and their application in the "core—nanoshell" systems synthesized by the molecular layering

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Russian Chemical Bulletin Aims and scope

Abstract

In connection with the development of nanotechnology in the last 15—20 years, the method of molecular layering (ML), created in the middle of the last century in the USSR, has attracted increasing attention. The features of structural-dimensional effects in the products obtained by new chemical nanotechnology and promising directions of their practical application in "core—nanoshell" compositions are considered in the review. In accordance with the synthetic capabilities of the ML method, the functional properties of the "core—nanoshell" type materials are affected by the "monolayer effect" and the substrate shielding effect, as well as the multicomponent nature of the system, and mutual structural coordination effect of the substrate and the build-up nanolayer. The review presents theoretical and experimental data on the application of the observed effects in the creation of shell pigments and fillers, modified sorbents, catalytic membrane reactors, nanodoped ceramic materials, polymers, quartz fibers with adjustable optical characteristics, electrets, etc.

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  1. St. Petersburg State Technological Institute (Technical University), 26 Moskovskii prosp., 190013, St. Petersburg, Russian Federation

    А. А. Malygin, А. А. Маlkov & Е. А. Sosnov

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  1. А. А. Malygin
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  2. А. А. Маlkov
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Based on the Materials of the XX Mendeleev Congress on General and Applied Chemistry (September 26—30, 2016, Ekaterinburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1939—1962, November, 2017.

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Malygin, А.А., Маlkov, А.А. & Sosnov, Е.А. Structural-dimensional effects and their application in the "core—nanoshell" systems synthesized by the molecular layering. Russ Chem Bull 66, 1939–1962 (2017). https://doi.org/10.1007/s11172-017-1971-9

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