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Russian Chemical Bulletin

, Volume 65, Issue 4, pp 1027–1033 | Cite as

Synthesis and studies of benzoxazinesiloxanes

  • V. N. Sokolik
  • Sh. F. Gizatullin
  • I. M. Raigorodskii
  • V. M. Kopylov
  • T. R. Salikhov
Full Articles

Abstract

A synthesis of organosilicon 1,3-benzoxazines (BZ-Si) was accomplished by the reaction of organic phenols, paraformaldehyde and 3-aminopropyl(trialkoxy)silanes, as well as organosilicon phenols of the general formula R´[SiMe2O]n[SiMeRO]mSiMe2R´ (R´ is 4-hydroxy-3methoxyphenylpropyl-, R is methylor 4-hydroxy-3-methoxyphenylpropyl), paraformaldehyde, and aniline (or monoethanolamine). The structure of BZ-Si was confirmed by NMR and IR spectroscopy. The studies of BZ-Si by DSC showed that the benzoxazine ring opening takes place in the temperature range 130—265 °C. The temperature of 5% mass loss of BZ-Si in air is within 220—270 °C (TGA).

Keywords

1,3-benzoxazines siloxanes NMR spectroscopy IR spectroscopy DSC TGA 

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • V. N. Sokolik
    • 1
  • Sh. F. Gizatullin
    • 1
  • I. M. Raigorodskii
    • 1
  • V. M. Kopylov
    • 1
  • T. R. Salikhov
    • 2
  1. 1.M. V. Lomonosov Moscow State University of Fine Chemical TechnologiesMoscowRussian Federation
  2. 2.All-Russian Scientific Research Institute of Aviation MaterialsMoscowRussian Federation

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