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Russian Chemical Bulletin

, Volume 65, Issue 4, pp 1023–1026 | Cite as

New organosilicon derivatives of some analytical reagents: sorbents and metallochromic agents

  • N. N. Vlasova
  • E. N. Oborina
  • L. I. Belousova
  • L. I. Larina
Full Articles

Abstract

A synthesis of organosilicon monomeric and polymeric derivatives of 1,4-phenylenediamine, 4-aminoantipyrine, and aniline, which are analytical agents possessing sorption properties, was accomplished. The synthesized organosilicon polymers were studied as sorbents of heavy metals FeIII, HgII and noble metals AgI, AuIII, RhIII, PdII, PtIV. Poly[(3-N-silsesquioxanylpropyl-4aminoantipyrine)] exhibited high sorption activity with respect to platinum group metals in comparison with poly[N,N´-bis(3-silsesquioxanylpropyl)-1,4-phenylenediamine]. The reaction of poly[(3-N-silsesquioxanylpropyl-4-aminoantipyrine)] practically with all the elements under study was accompanied by coloring. The starting monomer exhibited similar metallochromic properties.

Keywords

1,4-phenylenediamine 4-aminoantipyrine aniline carbofunctional organosilicon monomers polyorganylsilsesquioxanes metals sorbents 

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • N. N. Vlasova
    • 1
  • E. N. Oborina
    • 1
  • L. I. Belousova
    • 1
  • L. I. Larina
    • 1
  1. 1.A. E. Favorsky Irkutsk Institute of ChemistrySiberian Branch of the Russian Academy of SciencesIrkutskRussian Federation

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