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Russian Chemical Bulletin

, Volume 65, Issue 1, pp 200–202 | Cite as

First example of [6π+2π] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene catalyzed by CoI compounds

  • V. A. D’yakonov
  • G. N. Kadikova
  • G. F. Gazizullina
  • U. M. Dzhemilev
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Abstract

A stereoselective [6π+2π] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene in the presence of a multi-component catalytic system CoI2/dppe/Zn/ZnI2, which led to the formation of substituted (E)-bicyclo[4.2.2]deca-2,4,7-trienes in 76—87% yields, was accomplished for the first time.

Keywords

homogeneous metal complex catalysis cycloaddition 1,3,5,7-cyclooctatetraene 1,2-dienes cobalt(II) iodide bicyclo[4.2.2]deca-2,4,7-trienes 

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • V. A. D’yakonov
    • 1
  • G. N. Kadikova
    • 1
  • G. F. Gazizullina
    • 1
  • U. M. Dzhemilev
    • 1
  1. 1.Institute of Petrochemistry and CatalysisRussian Academy of SciencesUfaRussian Federation

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