Russian Chemical Bulletin

, Volume 65, Issue 1, pp 75–81 | Cite as

Thermodynamics of the terpolymer of carbon monoxide, ethylene, and 1-butene

  • N. N. Smirnova
  • O. N. Golodkov
  • A. V. Markin
  • L. Ya. Tsvetkova
  • P. D. Afonin
  • O. N. Smirnova
  • E. A. Zakharychev
  • G. P. Belov
Full Articles


The heat capacity and the temperatures and enthalpies of physical transformations of the alternating terpolymer of carbon monoxide, ethylene, and 1-butene (the content of butene units is 10.7 mol.%) were studied by adiabatic and differential scanning calorimetry in the temperature range from 6 to 520 K. The energy of terpolymer combustion was measured at 298.15 K on an calorimeter with an isothermal shell and static bomb. The standard thermodynamic functions C°p(T), H°(T)–H°(0), S°(T)–S°(0), and G°(T)–H°(0) for the range from Т → 0 to 400 K, the standard enthalpy of combustion, and the thermodynamic parameters of formation of the partially crystalline CO—ethylene—1-butene terpolymer at 298.15 K, as well as the thermodynamic characteristics of its synthesis in the range from T → 0 to 400 K were calculated.


ternary alternating copolymer energy of combustion thermodynamic functions thermodynamic characteristics of copolymerization 


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© Springer Science+Business Media New York 2016

Authors and Affiliations

  • N. N. Smirnova
    • 1
  • O. N. Golodkov
    • 2
  • A. V. Markin
    • 1
  • L. Ya. Tsvetkova
    • 1
  • P. D. Afonin
    • 1
  • O. N. Smirnova
    • 1
  • E. A. Zakharychev
    • 1
  • G. P. Belov
    • 2
  1. 1.Lobachevsky State University of Nizhni NovgorodNizhny NovgorodRussian Federation
  2. 2.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow regionRussian Federation

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