Russian Chemical Bulletin

, Volume 64, Issue 12, pp 2786–2790 | Cite as

Hydrogenation of aromatic hydrocarbons in a mixture with thiophene on sulfided Pd/Al2O3 catalysts

  • A. L. Tarasov
  • O. V. Malova
  • I. I. Lishchiner
Full Articles


The activity and stability of aluminum-palladium catalysts in the hydrogenation of aromatic hydrocarbons mixed with thiophene were studied. The catalysts were obtained by impregnation of γ-A2O3 with aqueous solutions of salts of palladium complexes. Preliminary sulfiding followed by oxidative activation of Pd/Al2O3 catalysts were found to favor the formation of such palladium state on the surface at which the hydrogenation of aromatic hydrocarbons in the presence of sulfur-containing impurities proceeds without a noticeable change in the activity with time. IR spectroscopy showed that the palladium metal surface fragments forming CO complexes with a characteristic absorption band at 1998 cm–1 are resistant to poisoning with sulfur-containing compounds in the hydrogenation of aromatic hydrocarbons.

Key words

hydrogenation aromatic compounds sulfiding thiophene palladium 


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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • A. L. Tarasov
    • 1
  • O. V. Malova
    • 2
  • I. I. Lishchiner
    • 2
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Joint Institute for High TemperaturesRussian Academy of SciencesMoscowRussian Federation

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