Russian Chemical Bulletin

, Volume 64, Issue 11, pp 2667–2677 | Cite as

Hyperbranched polyester poly(3-diethylamino)propionates and their copper(ii) complexes

  • M. P. Kutyreva
  • A. R. Gataulina
  • G. A. Kutyrev
  • N. A. Ulakhovich
  • A. V. Surnova
  • S. V. Yurtaeva
Full Articles


Novel polydentate ligands were obtained from second and third generation hyperbranched polyesters containing terminal (3-diethylamino)propionate groups. Polynuclear CuII complexes with these ligands were synthesized. The degree of diethylamination of the polyesters increases when moving from the second to the third generation (from 56 to 81%). In polynuclear complexes, the ratios of Cu to hyperbranched ligand are 6 : 1 and 13 : 1 for second and third generation polyester polyamines, respectively. It was demonstrated using IR and ESR spectroscopy that each coordination polyhedron in the complexes is an isolated paramagnetic center of the formula CuN2O2Solv2 (Solv = H2O, DMSO).

Key words

hyperbranched polyester poly(3-diethylamino)propionates copper(II) complexes ionization complexation 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    C. Gao, D. Yan, Progr. Polym. Sci., 2004, 29, 183.CrossRefGoogle Scholar
  2. 2.
    A. W. Bosman, A. P. H. J. Schenning, R. A. J. Janssen, E. W. Meijer, Chem. Ber. Recl., 1997, 130, 725.CrossRefGoogle Scholar
  3. 3.
    M. Haüβler, H. Dong, B. Z. Tang, Inorganic and Organometallic Macromolecules: Design and Applications, Springer, New York, 2008, 21.Google Scholar
  4. 4.
    C. Gao, Y. Xu, D. Yan, W. Chen, Biomacromolecules, 2003, 4, 704.CrossRefGoogle Scholar
  5. 5.
    Z. Zhong, Y. Song, J. F. Engbersen, W. E. Hennink, J. Feijen, J. Controlled Release, 2005, 109, 317.CrossRefGoogle Scholar
  6. 6.
    C. Lin, Z. Zhong, M. C. Lok, X. Jiang, W. E. Hennink, J. Feijen, Bioconjugate Chem., 2007, 18, 138.CrossRefGoogle Scholar
  7. 7.
    M. Scholl, Z. Kadlecova, Prog. Polym. Sci., 2009, 34, 24.CrossRefGoogle Scholar
  8. 8.
    R. Arote, T.-H. Kim, Y.-K. Hwang, H.-L. Jiang, J.-W. Nah, M.-H. Cho, C.-S. Cho, Biomaterials, 2007, 28, 735.CrossRefGoogle Scholar
  9. 9.
    R. Reul, J. Nguyen, T. Kissel, J. Biomater., 2009, 30, 581.CrossRefGoogle Scholar
  10. 10.
    M. F. Ottaviani, F. Montalti, N. J. Turro, D. A. Tomalia, J. Phys. Chem. B, 1997, 101, 158.CrossRefGoogle Scholar
  11. 11.
    K. A. Krot, A. F. Danil de Namor, A. Aguilar-Cornejo, K. B. Nolan, Inorg. Chim. Acta, 2005, 358, 3497.CrossRefGoogle Scholar
  12. 12.
    A. Mecke, S. Uppuluri, T. M. Sassanella, Chem. Phys. Lipids, 2004, 132, 3.CrossRefGoogle Scholar
  13. 13.
    H. Kobayashi, S. Kawamato, S. K. Jo, Bioconjug. Chem., 2003, 14, 388.CrossRefGoogle Scholar
  14. 14.
    M. P. Kutyreva, A. R. Gataulina, G. A. Kutyrev, I. S. Nizamov, N. A. Ulakhovich, Russ. J. Gen. Chem. (Engl. Transl.), 2011, 81, 960 [Zh. Obshch. Khim., 2011, 81, 873].CrossRefGoogle Scholar
  15. 15.
    M. P. Kutyreva, A. R. Gataulina, G. A. Kutyrev, I. S. Nizamov, N. A. Ulakhovich, Russ. J. Gen. Chem. (Engl. Transl.), 2011, 81, 1535 [Zh. Obshch. Khim., 2011, 81, 1187].CrossRefGoogle Scholar
  16. 16.
    M. P. Kutyreva, G. Sh. Usmanova, N. A. Ulakhovich, O. I. Medvedeva, V. V. Syakaev, S. A. Ziganshina, G. A. Kutyrev, Polym. Sci., Ser. B (Engl. Transl.), 2013, 55, 201 [Vysokomol. Soedin., Ser. B, 2013, 55, 463].CrossRefGoogle Scholar
  17. 17.
    M. P. Kutyreva, N. A. Ulakhovich, A. R. Gataulina, A. A. Khannanov, O. A. Malinovskikh, S. V. Yurtaeva, E. P. Medyantseva, Russ. Chem. Bull. (Int. Ed.), 2014, 63, 239 [Izv. Akad. Nauk, Ser. Khim., 2014, 239].CrossRefGoogle Scholar
  18. 18.
    A. R. Gataulina, A. A. Khannanov, O. A. Malinovskikh, O. V. Bondaŕ, N. A. Ulakhovich, M. P. Kutyreva, Russ. J. Gen. Chem. (Engl. Transl.), 2013, 83, 2269 [Zh. Obshch. Khim., 2013, 83, 1984].CrossRefGoogle Scholar
  19. 19.
    E. Zagar, M. Zigon, Macromolecules, 2002, 35, 9913.CrossRefGoogle Scholar
  20. 20.
    E. Zagar, M. Zigon, Progr. Polym. Sci., 2011, 36, 53.CrossRefGoogle Scholar
  21. 21.
    A. M. Toroptseva, K. V. Belogorodskaya, V. M. Bondarenko, Laboratornyi praktikum po khimii i tekhnologii vysokomolekulyarnykh soedinenii [The Laboratory Manual of Polymer Chemistry and Technology], Khimiya, Moscow, 1972, 360 pp. (in Russian).Google Scholar
  22. 22.
    Yu. I. Salńikov, A. N. Glebov, F. V. Devyatov, Poliyadernye kompleksy v rastvorakh [Polynuclear Complexes in Solutions], Kazan State University Press, Kazan, 1989, 288 pp. (in Russian).Google Scholar
  23. 23.
    W. B. Lewis, M. Alei, L. O. Morgan, J. Chem. Phys., 1966, 44, 2409.CrossRefGoogle Scholar
  24. 24.
    A. I. Kokorin, N. A. Vengerova, Yu. E. Kirsh, K. I. Zamaraev, Dokl. Akad. Nauk SSSR, 1972, 202, 597 [Dokl. Chem. USSR (Engl. Transl.), 1972, 202].Google Scholar
  25. 25.
    G. M. Larin, V. A. Kolosov, Yu. N. Dubrov, Koord. Khim., 1978, 4, 35 [Sov. J. Coord. Chem. (Engl. Transl.), 1978, 4].Google Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • M. P. Kutyreva
    • 1
  • A. R. Gataulina
    • 1
  • G. A. Kutyrev
    • 2
  • N. A. Ulakhovich
    • 1
  • A. V. Surnova
    • 1
  • S. V. Yurtaeva
    • 3
  1. 1.Kazan (Volga Region) Federal UniversityKazanRussian Federation
  2. 2.Kazan National Research Technological UniversityKazanRussian Federation
  3. 3.E. K. Zavoisky Kazan Institute of Physical EngineeringKazan Research Center of the Russian Academy of SciencesKazanRussian Federation

Personalised recommendations