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Russian Chemical Bulletin

, Volume 64, Issue 11, pp 2562–2572 | Cite as

The mechanisms of porphyrin complexation in solvents and polymer matrices

  • O. I. Koifman
  • I. P. Trifonova
  • V. A. Burmistrov
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  • 32 Downloads

Abstract

Experimental data for the reactions of porphyrins with metal salts in various media are analyzed; possible mechanisms of the reactions are discussed. The experimental findings as well as quantum chemical calculations suggest that the most probable reaction mechanism should involve the formation of a SAT complex and a substantial deformation of the macrocycle.

Key words

porphyrins macroheterocycles kinetics reactivity polymer matrices 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • O. I. Koifman
    • 1
    • 2
  • I. P. Trifonova
    • 1
  • V. A. Burmistrov
    • 1
  1. 1.Research Institute of Macroheterocyclic CompoundsIvanovo State University of Chemistry and TechnologyIvanovoRussian Federation
  2. 2.Institute of Solution ChemistryRussian Academy of SciencesIvanovoRussian Federation

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