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Russian Chemical Bulletin

, Volume 64, Issue 9, pp 2265–2268 | Cite as

Synthesis of [(N-acetyl-N-methyl)aminomethyl](dimethyl)silyl nitrate

  • N. F. Lazareva
  • V. V. Belyaeva
  • I. M. Lazarev
Brief Communications
  • 27 Downloads

Abstract

Transsilylation of N-methyl-N-trimethylsilylacetamide with chloromethyl(dimethyl)silylnitrate ClCH2SiMe2ONO2 led to the formation of (N-acetyl-N-methyl)aminomethyl](dimethyl)silyl nitrate, the (O–Si)-chelate with the intramolecular coordination C=O→Si bond. Spectral characteristics of this compound and the reaction product of N-[chloro(dimethyl)silylmethyl]-N-methylacetamide with silver nitrate are identical.

Key words

nitric acid silyl esters chloromethyl(dimethyl)silyl nitrate transsilylation (O–Si)-chelates [(N-acetyl-N-methyl)aminomethyl](dimethyl)silyl nitrate 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • N. F. Lazareva
    • 1
  • V. V. Belyaeva
    • 1
  • I. M. Lazarev
    • 1
  1. 1.A. E. Favorsky Irkutsk Institute of ChemistrySiberian Branch of the Russian Academy of SciencesIrkutskRussian Federation

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