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Russian Chemical Bulletin

, Volume 64, Issue 8, pp 1982–1985 | Cite as

Solubilization of new calix[4]resorcinols with amino acid substituents at the upper rim in surfactant micellar solutions

  • G. A. Gainanova
  • A. M. Bekmukhametova
  • M. N. Saifutdinova
  • E. L. Gavrilova
  • L. Ya. Zakharova
  • O. G. Sinyashin
Brief Communications

Abstract

A spectrophotometric method was used to select conditions for the development of aqueous systems based on new calix[4]resorcinols containing amino acid moieties at the upper rim and heptyl or nonyl substituents at the lower rim. It was found that the additives of N-metylglucamine lead to the increase in the solubility in water of the macrocycles under study. Traditional surfactants (cetyltrimetylammonium bromide and sodium dodecylsulfate) considerably increase the solubility of calix[4]resorcinols under study due to their solubilization in the nonpolar micelle core when the concentration of the amphiphilic compounds is half as large as the concentration of N-metylglucamine.

Key words

solubilization calix[4]resorcinol surfactants N-methylglucamine 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • G. A. Gainanova
    • 1
  • A. M. Bekmukhametova
    • 1
  • M. N. Saifutdinova
    • 1
  • E. L. Gavrilova
    • 1
  • L. Ya. Zakharova
    • 1
    • 2
  • O. G. Sinyashin
    • 1
    • 2
  1. 1.Kazan National Research Technological UniversityKazanRussian Federation
  2. 2.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Scientific Center of the Russian Academy of SciencesKazanRussian Federation

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