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Russian Chemical Bulletin

, Volume 64, Issue 8, pp 1975–1977 | Cite as

Reactions of 2-aminothiophenol with pyridineand imidazolecarboxaldehydes

  • E. S. Barskaya
  • E. K. Beloglazkina
  • A. G. Mazhuga
  • I. V. Yudin
  • N. V. Zyk
Brief Communications

Abstract

Reflux of imidazole-2-carboxaldehyde, 1-methylimidazole-2-carboxaldehyde, imidazole4-carboxaldehyde, or 5-bromopyridine-2-carboxaldehyde with 2-aminothiophenol in ethanol in the presence of air oxygen for 1.5 h affords the corresponding 2-hetaryl-substituted 1,3-benzothiazoles. The reaction of 2-(1-methyl-1H-imidazol-2-yl)-1,3-benzothiazole with Cu(ClO4)2•6H2O gives bis[2-(1-methyl-1H-imidazol-2-yl)-1,3-benzothiazole]copper(ii) diperchlorate monohydrate.

Key words

benzothiazoles 2-pyridinecarboxaldehyde imidazolecarboxaldehyde copper(ii) complex 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • E. S. Barskaya
    • 1
  • E. K. Beloglazkina
    • 1
  • A. G. Mazhuga
    • 1
  • I. V. Yudin
    • 1
  • N. V. Zyk
    • 1
  1. 1.Chemistry DepartmentM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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