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Russian Chemical Bulletin

, Volume 64, Issue 2, pp 395–404 | Cite as

Alkylation of NH-, OH-, and SH-acids in the presence of potassium carbonate

1. Functionalization of chloromethyl group of alkoxy-substituted aromatic aldehydes
  • D. S. Khachatryan
  • A. L. Razinov
  • A. V. Kolotaev
  • S. K. Belus´
  • K. R. Matevosyan
Full Articles

Abstract

An easily scalable, economocal, and more safe method for the preparation of 3-chloromethyl-4-methoxybenzaldehyde was developed. The latter was subjected to reactions with NH-, OH-, and SH-acids in the presence of potassium carbonate to obtain new aromatic aldehydes in high yields.

Keywords

3-chloromethyl-4-methoxybenzaldehyde NH-, OH-, and SH-acids alkylation potassium carbonate aromatic aldehydes 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • D. S. Khachatryan
    • 1
  • A. L. Razinov
    • 1
  • A. V. Kolotaev
    • 1
  • S. K. Belus´
    • 1
  • K. R. Matevosyan
    • 2
  1. 1.Labor Red Banner order Federal State Unitary Enterprise “Research Institute of Chemical Reactants and Ultrapure Compounds (IREA)”MoscowRussian Federation
  2. 2.D. I. Mendeleev University of Chemical Technology of RussiaMoscowRussian Federation

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