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Russian Chemical Bulletin

, Volume 64, Issue 2, pp 366–374 | Cite as

Preparation, structure, and main properties of bimolecular crystals CL-20—DNP and CL-20—DNG

  • T. K. Goncharov
  • Z. G. Aliev
  • S. M. Aldoshin
  • D. V. Dashko
  • A. A. Vasil´eva
  • N. I. Shishov
  • Yu. M. Milekhin
Full Articles

Abstract

New bimolecular crystals of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) with 2,4-dinitro-2,4-diazapentane (DNP) and 2,4-dinitro-2,4-diazaheptane (DNG) were obtained in a ratio of 2 : 1 and 1 : 1, respectively. Their X-ray diffraction analyses were carried out. The thermal stability, detonation characteristics, and sensitivity to friction of bimolecular crystal of CL-20 with DNP (CLD) were studied. The detonation characteristics of bimolecular crystal CLD are comparable with the properties of the known bimolecular crystal CL-20—HMX (2 : 1).

Keywords

2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane polycyclic nitroamine 2,4-dinitro-2,4-diazapentane 2,4-dinitro-2,4-diazaheptane crystallization X-ray diffraction analysis crystal and molecular structures energy bimolecular crystals thermal stability 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • T. K. Goncharov
    • 1
  • Z. G. Aliev
    • 1
  • S. M. Aldoshin
    • 1
  • D. V. Dashko
    • 2
  • A. A. Vasil´eva
    • 2
  • N. I. Shishov
    • 3
  • Yu. M. Milekhin
    • 3
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation
  2. 2.SKTB TekhnologSt. PetersburgRussian Federation
  3. 3.Federal Center of Double Technologies SoyuzDzerzhinskii, Moscow RegionRussian Federation

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