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Preparation, structure, and main properties of bimolecular crystals CL-20—DNP and CL-20—DNG

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Abstract

New bimolecular crystals of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) with 2,4-dinitro-2,4-diazapentane (DNP) and 2,4-dinitro-2,4-diazaheptane (DNG) were obtained in a ratio of 2 : 1 and 1 : 1, respectively. Their X-ray diffraction analyses were carried out. The thermal stability, detonation characteristics, and sensitivity to friction of bimolecular crystal of CL-20 with DNP (CLD) were studied. The detonation characteristics of bimolecular crystal CLD are comparable with the properties of the known bimolecular crystal CL-20—HMX (2 : 1).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    T. K. Goncharov, Z. G. Aliev & S. M. Aldoshin

  2. SKTB Tekhnolog, 33-A Sovetsky prosp., 193076, St. Petersburg, Russian Federation

    D. V. Dashko & A. A. Vasil´eva

  3. Federal Center of Double Technologies Soyuz, 42 ul. Zhukova, 140090, Dzerzhinskii, Moscow Region, Russian Federation

    N. I. Shishov & Yu. M. Milekhin

Authors
  1. T. K. Goncharov
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  2. Z. G. Aliev
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  3. S. M. Aldoshin
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  4. D. V. Dashko
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  5. A. A. Vasil´eva
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  6. N. I. Shishov
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  7. Yu. M. Milekhin
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Corresponding author

Correspondence to T. K. Goncharov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0366—0374, February, 2015.

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Goncharov, T.K., Aliev, Z.G., Aldoshin, S.M. et al. Preparation, structure, and main properties of bimolecular crystals CL-20—DNP and CL-20—DNG. Russ Chem Bull 64, 366–374 (2015). https://doi.org/10.1007/s11172-015-0870-1

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  • DOI: https://doi.org/10.1007/s11172-015-0870-1

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