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Russian Chemical Bulletin

, Volume 64, Issue 1, pp 196–201 | Cite as

A magnetic metal/polymer nanocomposite material based on poly(diphenylamine) and Fe3O4 nanoparticles

  • S. Zh. Ozkan
  • E. L. Dzidziguri
  • G. P. Karpacheva
  • P. A. Chernavskii
  • M. N. Efimov
  • G. N. Bondarenko
Full Articles

Abstract

It was discovered that IR heating of poly(diphenylamine) in the presence of FeCl3•6H2O in an inert atmosphere at 300–700 °C produces a metal polymer nanocomposite with Fe3O4 nanoparticles dispersed in polymer matrix. This is achieved by condensation of crystalline diphenylamine oligomers with evolution of hydrogen that promotes iron reduction. The formation of Fe3O4 nanoparticles was confirmed by X-ray powder diffraction. The magnetic and thermal properties of the Fe3O4—poly(diphenylamine) nanocomposite were examined. This nanocomposite material shows superparamagnetism and thermal stability.

Keywords

poly(diphenylamine) IR heating Fe3O4 metal polymer nanocomposite magnetic material 

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • S. Zh. Ozkan
    • 1
  • E. L. Dzidziguri
    • 2
  • G. P. Karpacheva
    • 1
  • P. A. Chernavskii
    • 3
  • M. N. Efimov
    • 1
  • G. N. Bondarenko
    • 1
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussian Federation
  2. 2.National University of Science and Technology “MISiS”MoscowRussian Federation
  3. 3.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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