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Fragmentation of disordered titanium monoxide of stoichiometric composition TiO

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Abstract

Fragmentation was carried out for coarse crystalline disordered titanium monoxide of stoichiometric composition TiO containing up to 16 at.% of structural vacancies in each titanium and oxygen sublattices. According to X-ray diffraction analysis, the fragmentation attained the nanometric size of titanium monoxide particles. In spite of the small size of the nanoparticles (about 30 nm) and high degree of induced microstrains of the crystal lattice (~0.57%), their atomic structure retained the main features of the disordered cubic structure of coarse crystalline titanium monoxide with the space group Fm-3m.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 ul. Pervomaiskaya, 620990, Ekaterinburg, Russian Federation

    A. A. Valeeva & A. A. Rempel

  2. Ural Federal University named after the First President of Russia B. N. Yeltsin, 19 ul. Mira, 620002, Ekaterinburg, Russian Federation

    A. A. Valeeva & A. A. Rempel

  3. Institute for Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17/III, A-8010, Graz, Austria

    H. Schröttner

Authors
  1. A. A. Valeeva
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  2. H. Schröttner
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  3. A. A. Rempel
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Correspondence to A. A. Valeeva.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2729–2732, December, 2014.

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Valeeva, A.A., Schröttner, H. & Rempel, A.A. Fragmentation of disordered titanium monoxide of stoichiometric composition TiO. Russ Chem Bull 63, 2729–2732 (2014). https://doi.org/10.1007/s11172-014-0806-1

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  • DOI: https://doi.org/10.1007/s11172-014-0806-1

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