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Modified approach to the Arduengo carbene complexes of silver

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Abstract

A straightforward reaction between 1,3-dimethyl-1H-imidazolium iodide (1) and AgF in acetonitrile (molar ratio 2: 3) results in bis[1,3-dimethyl-2,3-dihydro-1H-imidazol-2-ylidene-κC 2]silver(1+) hydrofluorides (2) and AgI in an almost quantitative yield. Hydrofluorides 2, namely, [(C5H8N2)2Ag]+[HF2]- (2a) and [(C5H8N2)2Ag]+[H2F3]- (2b), were isolated under different crystallization conditions. Crystal and molecular structures of hydrofluorides 2a and 2b as well as that of the initial salt 1 were established by X-ray diffraction analysis.

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Authors and Affiliations

  1. College of Chemistry, Leshan Normal University, Binhe 778, 614000, Leshan, Sichuan province, People’s Republic of China

    Chong Tian, Wanli Nie, Qiao Chen, Guofeng Sun & M. V. Borzov

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  1. Chong Tian
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  2. Wanli Nie
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  3. Qiao Chen
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  4. Guofeng Sun
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  5. M. V. Borzov
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Corresponding author

Correspondence to M. V. Borzov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2675—2680, December, 2014.

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Tian, C., Nie, W., Chen, Q. et al. Modified approach to the Arduengo carbene complexes of silver. Russ Chem Bull 63, 2675–2680 (2014). https://doi.org/10.1007/s11172-014-0797-y

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  • DOI: https://doi.org/10.1007/s11172-014-0797-y

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