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Alkyl (N,N-dibutylcarbamoylmethyl)methylphosphinates as new reagents for extraction and sorption of f-elements and technetium(VII) from acidic solutions

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Abstract

Liquid-phase extraction and sorption (solid-phase extraction) of AmIII, EuIII, UVI, and TcVII with alkyl (N,N-dibutylcarbamoylmethyl)methylphosphinates (ADM) from nitric acid solution were studied. The solvate numbers of extracted UVI, AmIII, EuIII, and TcVII complexes and the separation factors for AmIII/EuIII (f Am/Eu), TcVII/EuIII (f Tc/Eu), and UVI/TcVII (f U/Tc) pairs were determined. It was shown for the extraction of AmIII and sorption of PuIV that various ADM derivatives are most efficient for the extraction and sorption concentration of actinides: the heptyl derivative (C7) is efficient for extraction and the decyl derivative (C10) is most efficient for sorption.

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References

  1. W. W. Schulz, E. P. Horwitz, Sep. Sci. Technol., 1988, 23, 1191.

    Article  CAS  Google Scholar 

  2. E. G. Dzekun, B. F. Myasoedov, A. Y. Shadrin, Intern. Symp. Waste Management-92. Book of Abstracts, Tucson, USA, 1992, p. 805.

    Google Scholar 

  3. B. F. Myasoedov, M. K. Chmutova, I. V. Smirnov, A. Y. Shadrin, Intern. Conf. and Technology Exhibition Global´93 Amer. Nucl. Soc. Book of Abstracts, La Grange Park, IL, USA, 1993, p. 581.

    Google Scholar 

  4. E. P. Horwitz, R. Chiarizia, M. L. Dietz, H. Diamond, A. M. Essling, D. W. Gracyk, Anal. Chim. Acta, 1992, 266, 25.

    Article  CAS  Google Scholar 

  5. J. Mellado, M. Llaerado, G. Rawet, Anal. Chim. Acta, 2002, 458, 367.

    Article  CAS  Google Scholar 

  6. M. K. Chmutova, L. A. Ivanova, N. E. Kochetkova, N. P. Nesterova, B. F. Myasoedov, A. M. Rozen, Russ. Radiochem. (Engl. Transl.), 1995, 37 [Radiokhimiya, 1995, 37, 422].

    Google Scholar 

  7. V. P. Morgalyuk, G. A. Pribylova, D. E. Drozhko, L. A. Ivanova, R. M. Kalyanova, M. V. Logunov, O. I. Artyushin, I. G. Tananaev, S. I. Rovnyi, T. A. Mastryukova, B. F. Myasoedov, Russ. Radiochem. (Engl. Transl.), 2004, 46 [Radiokhimiya, 2004, 46, 128].

    Google Scholar 

  8. V. V. Kormachev, M. S. Fedoseev, Preparativnaya khimiya fosfora [Preparative Chemistry of Phosphorus], UrO RAN, Perm, 1992, p. 457 (in Russian).

    Google Scholar 

  9. T. A. Mastrukova, O. I. Artyushin, M. P. Pasechnik, E. V. Sharova, I. L. Odinets, V. P. Morgaluk, I. G. Tananaev, G. V. Myasoedova, B. F. Myasoedov, Russ. Chem. Bull. (Int. Ed.), 2005, 54, 2540. [Izv. Akad. Nauk, Ser. Khim., 2005, 2460].

    Article  Google Scholar 

  10. A. Weissberger, A. Proskauer, J. Riddick, A. Tups, Technique of Organic Chemistry, Vol. 7, Ed. A. Weissberger, Intersci. Publ., Inc., New York, 1955, 552 pp.

    Google Scholar 

  11. V. P. Morgalyuk, N. P. Molochnikova, G. V. Myasoedova, E. V. Sharova, O. I. Artyushin, I. G. Tananaev, Russ. Radiochem. (Engl. Transl.), 2005, 47 [Radiokhimiya, 2005, 47, 167].

    Google Scholar 

  12. N. Kabay, M. Demircioplu, H. Ekinci, M. Yüksel, M. Saplam, M. Streat, React. Func. Polym., 1998, 38, 219.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. P. Morgalyuk, O. I. Artyushin, E. V. Sharova & E. E. Nifant´ev

  2. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Building 4, 31 Leninsky prosp., 119071, Moscow, Russian Federation

    N. N. Popova & I. G. Tananaev

Authors
  1. V. P. Morgalyuk
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  2. N. N. Popova
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  3. O. I. Artyushin
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  4. E. V. Sharova
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  5. I. G. Tananaev
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  6. E. E. Nifant´ev
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Correspondence to V. P. Morgalyuk.

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Dedicated to the 60th anniversary of foundation of the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2541—2545, November, 2014.

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Morgalyuk, V.P., Popova, N.N., Artyushin, O.I. et al. Alkyl (N,N-dibutylcarbamoylmethyl)methylphosphinates as new reagents for extraction and sorption of f-elements and technetium(VII) from acidic solutions. Russ Chem Bull 63, 2541–2545 (2014). https://doi.org/10.1007/s11172-014-0773-6

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  • DOI: https://doi.org/10.1007/s11172-014-0773-6

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