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Russian Chemical Bulletin

, Volume 63, Issue 10, pp 2351–2354 | Cite as

17-Crown-5 ether condensed with 11-vertex nido-carborane

  • D. S. Perekalin
  • K. A. Lyssenko
  • A. R. Kudinov
Full Articles

Abstract

The reaction of easily accessible nido-carborane [nido-7,8-(HOCH2)2-7,8-C2B9H10]- with tetraethylene glycol tosylate produces nido-carborane sodium salt condensed with 17-crown-5 ether, Na[nido-7,8-O(CH2CH2OCH2CH2OCH2)2-7,8-C2B9H10]. The structures of solvate complexes of this crown ether with acetone, ethanol, and water were studied by X-ray diffraction analysis.

Key words

carboranes crown ethers sodium 

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References

  1. 1.
    J. Plešek, Chem. Rev., 1992, 92, 269–278.CrossRefGoogle Scholar
  2. 2.
    I. B. Sivaev, V. I. Bregadze, Coll. Czech. Chem. Commun., 1999, 64, 783–805.CrossRefGoogle Scholar
  3. 3.
    A. A. Semioshkin, I. B. Sivaev, V. I. Bregadze, Dalton Trans., 2008, 977–992.Google Scholar
  4. 4.
    B. Grüner, J. Plešek, J. Báča, J. F. Dozol, V. Lamare, I. Císařova, M. Bělohradský, J. áslavský, New J. Chem., 2002, 26, 867–875.CrossRefGoogle Scholar
  5. 5.
    B. Grüner, L. Mikulášek, J. Báča, I. Císařova, V. Böhmer, C. Danila, M. M. Reinoso-Garcia, W. Verboom, D. N. Reinhoudt, A. Casnati, R. Ungaro, Eur. J. Org. Chem., 2005, 2022–2039.Google Scholar
  6. 6.
    L. Mikulášek, B. Grüner, C. Danila, V. Bohmer, J. Cáslavský, P. Selucky, Chem. Commun., 2006, 4001–4003.Google Scholar
  7. 7.
    M. Yu. Stognii, G. S. Kazakov, I. B. Sivaev, V. I. Bregadze, Russ. Chem. Bull. (Int. Ed.), 2013, 62, 699–704 [Izv. Akad. Nauk, Ser. Khim., 2013, 699—704].CrossRefGoogle Scholar
  8. 8.
    B. Grüner, B. Bonnetot, H. Mongeot, Collect. Czech. Chem. Commun., 1997, 62, 1185–1204.CrossRefGoogle Scholar
  9. 9.
    F. Teixidor, C. Viñas, J. Rius, C. Miravitlles, J. Casabó, Inorg. Chem., 1990, 29, 149–152.CrossRefGoogle Scholar
  10. 10.
    F. Teixidor, J. Casabó, C. Viñas, E. Sanchez, L. Escriche, R. Kivekas, Inorg. Chem., 1991, 30, 3053–3058.CrossRefGoogle Scholar
  11. 11.
    F. Teixidor, J. Pedrajas, I. Rojo, C. Viñas, R. Kivekäs, R. Sillanpää, I. Sivaev, V. Bregadze, S. Sjöberg, Organometallics, 2003, 22, 3414–3423.CrossRefGoogle Scholar
  12. 12.
    H. D. Inerowicz, J. Chojnacki, A. Merz, T. Futterer, J. Incl. Phen. Macrocycl. Chem., 2000, 38, 123–132.CrossRefGoogle Scholar
  13. 13.
    A. R. Oki, B. Gilbes, F. Tarasyuk, T. J. Emge, Appl. Organomet. Chem., 2003, 17, 351–355.CrossRefGoogle Scholar
  14. 14.
    D. B. Dell’Amico, F. Calderazzo, N. Pasqualetti, R. Hubener, C. Maichle-Mossmer, J. Strahle, J. Chem. Soc., Dalton Trans., 1995, 3917–3924.Google Scholar
  15. 15.
    O. A. Filippov, A. M. Filin, V. N. Tsupreva, N. V. Belkova, A. Lledos, G. Ujaque, L. M. Epstein, E. S. Shubina, Inorg. Chem., 2006, 45, 3086–3096.CrossRefGoogle Scholar
  16. 16.
    N. V. Belkova, E. S. Shubina, L. M. Epstein, Acc. Chem. Res., 2005, 38, 624–631.CrossRefGoogle Scholar
  17. 17.
    D. Grafstein, J. Bobinski, J. Dvorak, H. Smith, N. Schwartz, M. S. Cohen, M. M. Fein, Inorg. Chem., 1963, 2, 1120–1125.CrossRefGoogle Scholar
  18. 18.
    A. I. Solomatina, L. G. Komarova, A. L. Rusanov, Russ. Chem. Bull. (Int. Ed.), 1995, 44, 1752–1754 [Izv. Akad. Nauk. Ser. Khim., 1995, 1821—1823].CrossRefGoogle Scholar
  19. 19.
    Y. Chen, G. L. Baker, J. Org. Chem., 1999, 64, 6870–6873.CrossRefGoogle Scholar
  20. 20.
    M. Ouchi, Y. Inoue, T. Kanzaki, T. Hakushi, J. Org. Chem., 1984, 49, 1408–1412.CrossRefGoogle Scholar
  21. 21.
    N. G. Luk’yanenko, A. V. Lobach, O. N. Leus, N. Yu. Titova, Russ. J. Org. Chem., 2002, 38, 895–899 [Zh. Org. Khim., 2002, 38, 937–941].CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • D. S. Perekalin
    • 1
  • K. A. Lyssenko
    • 1
  • A. R. Kudinov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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