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Russian Chemical Bulletin

, Volume 63, Issue 9, pp 2026–2035 | Cite as

Synthesis and studies of photochromic properties of spirobenzopyran carboxy derivatives and their model compounds as potential markers

  • A. V. Laptev
  • A. Yu. Lukin
  • N. E. Belikov
  • K. V. Zvezdin
  • O. V. Demina
  • V. A. Barachevsky
  • S. D. Varfolomeev
  • A. A. Khodonov
  • V. I. Shvets
Full Articles

Abstract

A number of photochromic markers, viz., spirobenzopyrans containing one or two active carboxy groups attached directly or through a spacer, as well as their model derivatives, were synthesized. The obtained compounds were characterized by instrumental methods of analysis. Spectrokinetic methods were used to study the behavior of the spirobenzopyran markers and the model derivatives in solutions in EtOH and toluene.

Keywords

spiropyran Horner-Emmons olefination Knoevenagel condensation photochromic markers 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • A. V. Laptev
    • 1
  • A. Yu. Lukin
    • 1
  • N. E. Belikov
    • 2
  • K. V. Zvezdin
    • 1
  • O. V. Demina
    • 2
  • V. A. Barachevsky
    • 3
  • S. D. Varfolomeev
    • 2
  • A. A. Khodonov
    • 1
    • 2
  • V. I. Shvets
    • 1
  1. 1.M. V. Lomonosov Moscow State University of Fine Chemical TechnologiesMoscowRussian Federation
  2. 2.N. M. Emanuel Institute of Biochemical PhysicsRussian Academy of SciencesMoscowRussian Federation
  3. 3.Center of PhotochemistryRussian Academy of SciencesMoscowRussian Federation

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