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Russian Chemical Bulletin

, Volume 63, Issue 8, pp 1837–1842 | Cite as

Acetylcholine as a catalyst of hydroperoxide decomposition to free radicals

  • D. A. Krugovov
  • E. A. Mengele
  • O. T. Kasaikina
Full Articles

Abstract

In organic solvents, acetylcholine chloride accelerates lipid oxidation and hydroperoxide decomposition to free radicals similarly to cationic surfactants. The rates of radical formation in the reaction of acetylcholine with cumyl, tert-butyl, and limonene hydroperoxides and hydrogen peroxide at 37 °C were estimated by the inhibitor method using different radical acceptors. In an aqueous medium, hygroscopic acetylcholine does not react with hydroperoxides.

Key words

acetylcholine hydroperoxides free radicals lipid oxidation method of inhibitors 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • D. A. Krugovov
    • 1
  • E. A. Mengele
    • 1
  • O. T. Kasaikina
    • 1
  1. 1.N. N. Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussian Federation

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