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Russian Chemical Bulletin

, Volume 63, Issue 7, pp 1515–1522 | Cite as

Assessment of the ability of metal chalcogenides to enter into ion-exchange reactions in aqueous solutions

  • L. N. Maskaeva
  • Z. I. Smirnova
  • V. F. Markov
Full Articles

Abstract

A versatile computational method for assessing the ability of metal chalcogenides to enter into ion-exchange reactions in aqueous solutions is proposed for the first time. Taking into account the ligand environment allows one to a priori predict the qualitative and quantitative composition of aqueous solutions favorable to mutual ion-exchange transformations of metal chalcogenides aimed at performing targeted synthesis of substitutional solid solutions and composite structures based on the title compounds.

Key words

metal chalcogenides ion exchange chemical deposition from aqueous media solubility substitutional solid solutions 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • L. N. Maskaeva
    • 1
    • 2
  • Z. I. Smirnova
    • 1
  • V. F. Markov
    • 1
    • 2
  1. 1.Ural Federal University named after the First President of Russia B. N. YeltsinEkaterinburgRussian Federation
  2. 2.Ural Institute of the State Fire Service of the Ministry of the Russian Federation for Affairs for Civil DefenseEmergencies, and Elimination of Consequences of Natural DisastersYekaterinburgRussian Federation

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