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Russian Chemical Bulletin

, Volume 63, Issue 4, pp 953–962 | Cite as

Reactivity of Cp*M (M = Co, Rh, Ir) half-sandwich complexes containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligand with organic azides

  • W. Zhong
  • H. Yan
  • Y. Li
  • V. I. Bregadze
Full Articles

Abstract

The reactivity of unsaturated 16-electron half-sandwich complexes Cp*M(S2C2B10H10) (Cp* is pentamethylcyclopentadienyl, M = Co, Rh, Ir) towards various organic azides was studied. The difference in the metal center and organic azides led to products with different coordination modes, which were characterized by 1H, 11B, and 13C NMR spectroscopy, IR spectroscopy, elemental analysis, and X-ray diffraction.

Key words

half-sandwich complex carborane reactivity organic azides 

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References

  1. 1.
    S. Bräse, C. Gil, K. Knepper, V. Zimmermann, Angew. Chem., Int. Ed., 2005, 44, 5188.CrossRefGoogle Scholar
  2. 2.
    E. F. V. Scriven, K. Turnbull, Chem. Rev., 1988, 88, 297.CrossRefGoogle Scholar
  3. 3.
    W. H. Binder, C. Kluger, Curr. Org. Chem., 2006, 10, 1791.CrossRefGoogle Scholar
  4. 4.
    H. C. Kolb, M. G. Finn, K. B. Sharpless, Angew. Chem., Int. Ed., 2001, 40, 2004.CrossRefGoogle Scholar
  5. 5.
    M. G. Fickes, W. M. Davis, C. C. Cummins, J. Am. Chem. Soc., 1995, 117, 6384.CrossRefGoogle Scholar
  6. 6.
    G. Proulx, R. G. Bergman, J. Am. Chem. Soc., 1995, 117, 6382.CrossRefGoogle Scholar
  7. 7.
    G. Albertin, S. Antoniutti, D. Baldan, J. Castro, S. Garcia-Fontan, Inorg. Chem., 2008, 47, 742.CrossRefGoogle Scholar
  8. 8.
    M. Barz, E. Herdtweck, W. R. Thiel, Angew. Chem., Int. Ed., 1998, 37, 2262.CrossRefGoogle Scholar
  9. 9.
    J. J. Curley, R. G. Bergman, T. D. Tilley, Dalton Trans., 2012, 41, 192.CrossRefGoogle Scholar
  10. 10.
    W. J. Evans, C. A. Traina, J. W. Ziller, J. Am. Chem. Soc., 2009, 131, 17473.CrossRefGoogle Scholar
  11. 11.
    Y. Yu, A. R. Sadique, J. M. Smith, T. R. Dugan, R. E. Cowley, W. W. Brennessel, C. J. Flaschenriem, E. Bill, T. R. Cundari, P. L. Holland, J. Am. Chem. Soc., 2008, 130, 6624.CrossRefGoogle Scholar
  12. 12.
    S. D. Brown, T. A. Betley, J. C. Peters, J. Am. Chem. Soc., 2003, 125, 322.CrossRefGoogle Scholar
  13. 13.
    G. Guillemot, E. Solari, C. Floriani, C. Rizzoli, Organometallics, 2001, 20, 607.CrossRefGoogle Scholar
  14. 14.
    K. E. Meyer, P. J. Walsh, R. G. Bergman, J. Am. Chem. Soc., 1995, 117, 974.CrossRefGoogle Scholar
  15. 15.
    R. I. Michelman, R. G. Bergman, R. A. Andersen, Organometallics, 1993, 12, 2741.CrossRefGoogle Scholar
  16. 16.
    A. F. Heyduk, K. J. Blackmore, N. A. Ketterer, J. W. Ziller, Inorg. Chem., 2005, 44, 468.CrossRefGoogle Scholar
  17. 17.
    G. Albertin, S. Antoniutti, A. Bacchi, A. Celebrin, G. Pelizzi, G. Zanardo, Dalton Trans., 2007, 661.Google Scholar
  18. 18.
    S. Cenini, G. La Monica, Inorg. Chim. Acta, 1976, 18, 279.CrossRefGoogle Scholar
  19. 19.
    G. L. Hillhouse, J. E. Bercaw, Organometallics, 1982, 1, 1025.CrossRefGoogle Scholar
  20. 20.
    G. L. Hillhouse, B. L. Haymore, Inorg. Chem., 1987, 26, 1876.CrossRefGoogle Scholar
  21. 21.
    M. Herberhold, H. Yan, W. Milius, B. Wrackmeyer, Angew. Chem., Int. Ed., 1999, 38, 3689.CrossRefGoogle Scholar
  22. 22.
    M. Herberhold, H. Yan, W. Milius, B. Wrackmeyer, Chem. Eur. J., 2000, 6, 3026.CrossRefGoogle Scholar
  23. 23.
    M. Herberhold, H. Yan, W. Milius, B. Wrackmeyer, Z. Anorg. Allg. Chem., 2000, 626, 1627.CrossRefGoogle Scholar
  24. 24.
    M. Herberhold, H. Yan, W. Milius, B. Wrackmeyer, J. Chem. Soc., Dalton Trans., 2001, 1782.Google Scholar
  25. 25.
    B. Wrackmeyer, H. Yan, W. Milius, M. Herberhold, Russ. Chem. Bull. (Int. Ed.), 2001, 50, 1518 [Izv. Akad. Nauk, Ser. Khim., 2001, 1444].CrossRefGoogle Scholar
  26. 26.
    M. Herberhold, H. Yan, W. Milius, B. Wrackmeyer, Chem. Eur. J., 2002, 8, 388.CrossRefGoogle Scholar
  27. 27.
    Y. Li, Q. Jiang, Y. Li, H. Yan, V. I. Bregadze, Inorg. Chem., 2010, 49, 4.CrossRefGoogle Scholar
  28. 28.
    Y. G. Li, H. D. Ye, G. Guoyiqibayi, Q. B. Jiang, Y. Z. Li, H. Yan, Sci. China: Chem., 2010, 53, 2129.CrossRefGoogle Scholar
  29. 29.
    B. H. Xu, X. Q. Peng, Y. Z. Li, H. Yan, Chem. Eur. J., 2008, 14, 9347.CrossRefGoogle Scholar
  30. 30.
    B. H. Xu, J. C. Tao, Y. Z. Li, S. H. Li, H. Yan, Organometallics, 2008, 27, 334.CrossRefGoogle Scholar
  31. 31.
    B. H. Xu, D. H. Wu, Y. Z. Li, H. Yan, Organometallics, 2007, 26, 4344.CrossRefGoogle Scholar
  32. 32.
    H. D. Ye, G. Y. Ding, M. S. Xie, Y. Z. Li, H. Yan, Dalton Trans., 2011, 40, 2306.CrossRefGoogle Scholar
  33. 33.
    G. Liu, J. Hu, J. Wen, H. Dai, Y. Li, H. Yan, Inorg. Chem., 2011, 50, 4187.CrossRefGoogle Scholar
  34. 34.
    W. Zhong, Q. Yang, Y. Shang, G. Liu, H. Zhao, Y. Li, H. Yan, Organometallics, 2012, 31, 6658.CrossRefGoogle Scholar
  35. 35.
    W. Zhong, M. Xie, Q. Jiang, Y. Li, H. Yan, Chem. Commun., 2012, 48, 2152.CrossRefGoogle Scholar
  36. 36.
    H. Katsuta, N. Noguchi, Y. Inomata, M. Kajitani, T. Akiyama, A. Sugimori, Chem. Lett., 1994, 23, 1165.CrossRefGoogle Scholar
  37. 37.
    M. Nomura, T. Yagisawa, C. Takayama, T. Sugiyama, Y. Yokoyama, K. Shimizu, A. Sugimori, M. Kajitani, J. Organomet. Chem., 2000, 611, 376.CrossRefGoogle Scholar
  38. 38.
    M. Nomura, A. Kawakita, H. Katsuta, C. Takayama, T. Sugiyama, Y. Yokoyama, M. Kajitani, J. Organomet. Chem., 2003, 681, 180.CrossRefGoogle Scholar
  39. 39.
    H. Dou, W. Zhong, L. Yang, T. Wang, H. Yan, Y. Hou, Bioorg. Med. Chem., 2012, 20, 4693.CrossRefGoogle Scholar
  40. 40.
    D. L. Davies, O. Al-Duaij, J. Fawcett, M. Giardiello, S. T. Hilton, D. R. Russell, Dalton Trans., 2003, 4132.Google Scholar
  41. 41.
    E. Kumaran, V. S. Sridevi, W. K. Leong, Organometallics, 2010, 29, 6417.CrossRefGoogle Scholar
  42. 42.
    D. H. Kim, J. J. Ko, K. Park, S. G. Cho, S. O. Kang, Organometallics, 1999, 18, 2738.CrossRefGoogle Scholar
  43. 43.
    J. Y. Bae, Y. I. Park, J. J. Ko, K. I. Park, S. I. Cho, S. O. Kang, Inorg. Chim. Acta, 1999, 289, 141.CrossRefGoogle Scholar
  44. 44.
    L. McElweewhite, D. A. Dougherty, J. Am. Chem. Soc., 1984, 106, 3466.CrossRefGoogle Scholar
  45. 45.
    D. Hebel, D. C. Furlano, R. S. Phillips, S. Koushik, C. R. Creveling, K. L. Kirk, Bioorg. Med. Chem. Lett., 1992, 2, 41.CrossRefGoogle Scholar
  46. 46.
    S. G. Alvarez, M. T. Alvarez, Synthesis, 1997, 413.Google Scholar
  47. 47.
    G. M. Sheldrick, SADABS, 1998, Göttingen University, Göttingen (Germany).Google Scholar
  48. 48.
    G. M. Sheldrick, SHELXS-97, Göttingen University, Göttingen (Germany).Google Scholar
  49. 49.
    G. M. Sheldrick, Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, 64, 112.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical EngineeringNanjing UniversityNanjing, JiangsuChina
  2. 2.College of Biological, Chemical Sciences and EngineeringJiaxing UniversityJiaxing, ZhejiangChina
  3. 3.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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