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Reactions of alkyl compounds of zinc, cadmium, and gallium with dysprosium, neodymium, and thulium diiodides

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Abstract

The ethyl complexes of dysprosium DyI2Et(DME)2 and DyIEt2(DME)2 were synthesized by the reaction of DyI2 with ZnEt2 in dimethoxyethane. The complexes were isolated as pale yellow crystals. According to the X-ray diffraction data, these compounds contain, in addition to DyI2Et(DME)2 and DyIEt2(DME)2, triiodide DyI3(DME)2 (1). The reactions of CdMe2 with NdI2, DyI2, and TmI2 proceed in a similar way and afford methyl iodide complexes of lanthanides. The reaction of GaEt3 with DyI2 gave the ionic complex of trivalent dysprosium [GaEt4]−[DyI2(THF)5]+ (2).

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References

  1. W. J. Evans, B. L. Davis, Chem. Rev., 2002, 102, 2119

    Article  CAS  Google Scholar 

  2. F. Nief, D. Turcitu, L. Ricard, Chem. Commun., 2002, 1646

    Google Scholar 

  3. L. J. Bowman, K. Izod, W. Clegg, R. W. Harrington, Organometallics, 2007, 26, 2646

    Article  CAS  Google Scholar 

  4. M. N. Bochkarev, Coord. Chem. Rev., 2004, 248, 835.

    Article  CAS  Google Scholar 

  5. M. N. Bochkarev, A. A. Fagin, G. V. Khoroshenτkov, Russ. Chem. Bull., Int. Ed., 2002, 51, 1909 [Izv. Akad. Nauk, Ser. Khim., 2002, 1757].

    Article  CAS  Google Scholar 

  6. M. Szostak, M. Spain, D. J. Procter, Angew. Chem., Int. Ed. Engl., 2013, 52, 7237.

    Article  CAS  Google Scholar 

  7. M. N. Bochkarev, G. V. Khoroshenkov, H. Schumann, S. Dechert, J. Am. Chem. Soc., 2003, 125, 2894.

    Article  CAS  Google Scholar 

  8. M. E. Burin, M. V. Smirnova, G. K. Fukin, E. V. Baranov, M. N. Bochkarev, Eur. J. Inorg. Chem., 2006, 351.

    Google Scholar 

  9. T. Sanden, M. T. Gamer, A. A. Fagin, V. A. Chudakova, S. N. Konchenko, I. L. Fedushkin, P. W. Roesky, Organometallics, 2012, 31, 4331.

    Article  CAS  Google Scholar 

  10. M. N. Bochkarev, L. V. Pankratov, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987, 36, 1717 [Izv. Akad. Nauk SSSR, Ser. Khim., 1987, 1852].

    Article  Google Scholar 

  11. T. V. Balashova, G. V. Khoroshenτkov, D. M. Kuzyaev, I. L. Eremenko, G. G. Aleksandrov, G. K. Fukin, M. N. Bochkarev, Russ. Chem. Bull., Int. Ed., 2004, 53, 825 [Izv. Akad. Nauk, Ser. Khim., 2004, 789].

    Article  CAS  Google Scholar 

  12. M. N. Bochkarev, A. A. Fagin, N. O. Druzhkov, V. K. Cherkasov, M. A. Katkova, J. Organomet. Chem., 2010, 695, 2774–2780.

    Article  CAS  Google Scholar 

  13. A. J. Wooles, O. J. Cooper, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle, Organometallics, 2010, 29, 2315–2321.

    Article  CAS  Google Scholar 

  14. Jaroschik, F. Nief, X.-F. Le Goff, Polyhedron, 2009, 28, 2744–2748.

    Article  CAS  Google Scholar 

  15. L. Lukesova, B. D. Ward, S. Bellemin-Laponnaz, H. Wadepohl, L. H. Gade, Organometallics, 2007, 26, 4652.

    Article  CAS  Google Scholar 

  16. S. Harder, C. Ruspic, N. N. Bhriain, F. Berkermann, M. Schurmann, Z. Naturforsch., Teil. B, 2008, 63, 267.

    Google Scholar 

  17. M. N. Bochkarev, A. A. Fagin, Chem. Eur. J., 1999, 5, 2990.

    Article  CAS  Google Scholar 

  18. SAINTPlus Data Reduction and Correction Program, v. 6.02a, Bruker AXS, Madison, WI, 2000.

  19. Data Collection, Reduction and Correction Program, CrysalisPro — Software Package Agilent Technologies, 2012.

  20. G. M. Sheldrick, SADABS, v. 2.01, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, WI, 1998.

    Google Scholar 

  21. SCALE3 ABSPACK: Empirical Absorption Correction, CrysalisPro — Software Package Agilent Technologies, 2012.

  22. G. M. Sheldrick, SHELXTL, v. 6.12, Structure Determination Software Suite, Bruker AXS, Madison, WI, 2000.

    Google Scholar 

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    A. A. Fagin, M. A. Samsonov, G. K. Fukin, T. V. Balashova & M. N. Bochkarev

Authors
  1. A. A. Fagin
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  2. M. A. Samsonov
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  3. G. K. Fukin
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  4. T. V. Balashova
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  5. M. N. Bochkarev
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Corresponding author

Correspondence to M. N. Bochkarev.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0833–0836, April, 2014.

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Fagin, A.A., Samsonov, M.A., Fukin, G.K. et al. Reactions of alkyl compounds of zinc, cadmium, and gallium with dysprosium, neodymium, and thulium diiodides. Russ Chem Bull 63, 833–836 (2014). https://doi.org/10.1007/s11172-014-0517-7

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  • DOI: https://doi.org/10.1007/s11172-014-0517-7

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