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X-ray photoelectron spectroscopy study of the charge and spin states of atoms in the tetranuclear copper(II) complex with the nitroxyl radical (L) of the composition Cu4(OH)2(OAc)4(DMF)2(L)2

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Abstract

The charge and spin states of atoms in the copper(II) complex with the nitroxyl radical (L) of the composition Cu4(OH)2(OAc)4(DMF)2(L)2 were studied by X-ray photoelectron spectroscopy and compared with the data of quantum chemical calculations. The spectra of copper represent a superposition of the |C−13d9〉 and |C−13d10 L〉 electronic states (C−1 = 2p5 or 3s1). All copper ions in the complex have the close-lying charge and spin states.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    L. N. Mazalov, N. A. Kryuchkova & A. D. Fedorenko

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    L. N. Mazalov & N. A. Kryuchkova

  3. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrentéva, 630090, Novosibirsk, Russian Federation

    A. V. Kalinkin

  4. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    E. V. Tretyakov

Authors
  1. L. N. Mazalov
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  2. N. A. Kryuchkova
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  3. A. D. Fedorenko
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  4. A. V. Kalinkin
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  5. E. V. Tretyakov
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Corresponding author

Correspondence to N. A. Kryuchkova.

Additional information

According to the materials of the International Conference “Organometallic and Coordination Chemistry: Fundamental and Applied Aspects” (September 1–7, 2013, Nizhny Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0826–0832, April, 2014.

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Mazalov, L.N., Kryuchkova, N.A., Fedorenko, A.D. et al. X-ray photoelectron spectroscopy study of the charge and spin states of atoms in the tetranuclear copper(II) complex with the nitroxyl radical (L) of the composition Cu4(OH)2(OAc)4(DMF)2(L)2 . Russ Chem Bull 63, 826–832 (2014). https://doi.org/10.1007/s11172-014-0516-8

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  • DOI: https://doi.org/10.1007/s11172-014-0516-8

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