Russian Chemical Bulletin

, Volume 63, Issue 3, pp 751–753 | Cite as

Synthesis of aromatic polyamides from dinitriles and bisphenols in ionic liquids

Full Articles


initriles react with bisphenols at 160 °C in ionic liquid (1-butyl-3-methylimidazolium heptachlorodialuminate) to give aromatic polyamides. The polymers obtained are completely soluble in concentrated sulfuric acid and, when heated, in amide-type solvents.

Key words

aromatic polyamides ionic liquids dinitriles bisphenols the Chapman rearrangement 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    V. V. Sokolov, V. D. Gerasimov, V. M. Savinov, V. K. Belyakov, Termostoikie aromaticheskie poliamidy [Heat-Resistant Aromatic Polyamides], Khimiya, Moscow, 1975, 237 pp. (in Russian).Google Scholar
  2. 2.
    V. F. Burdukovskii, D. M. Mognonov, Russ. Chem. Bull. (Int. Ed.), 2009, 58, 2400 [Izv. Akad. Nauk, Ser. Khim., 2009, 2323].CrossRefGoogle Scholar
  3. 3.
    C. Decastro, E. Sauvage, M. H. Valkenberg, W. F. Holderich, J. Catal., 2000, 196, 86.CrossRefGoogle Scholar
  4. 4.
    P. Wasserscheid, T. Welton, Ionic Liquids in Synthesis, Wiley-VCH, Weinheim, 2007.CrossRefGoogle Scholar
  5. 5.
    L. M. Kustov, T. V. Vasina, V. A. Ksenofontov, Ross. Khim. Zh., 2004, 48, 13 [Mendeleev Chem. J., 2004].Google Scholar
  6. 6.
    C. Reichardt, T. Welton, Solvents and Solvent Effects in Organic Chemistry, Wiley-VCH Verlag & Co. KGaA, Weinheim, 2011.Google Scholar
  7. 7.
    B. Ch. Kholkhoev, V. F. Burdukovskii, D. M. Mognonov, Russ. Chem. Bull. (Int. Ed.), 2010, 59, 2159 [Izv. Akad. Nauk, Ser. Khim., 2010, 2104].CrossRefGoogle Scholar
  8. 8.
    V. F. Burdukovskii, B. Ch. Kholkhoev, D. M. Mognonov, Izv. Akad. Nauk, Ser. Khim., 2013, 2263 [Russ. Chem. Bull. (Int. Ed.), 2013, 62, 2263].Google Scholar
  9. 9.
    J. W. Schulenberg, S. Archer, The Chapman Rearrangement in Organic Reactions, 1965, Vol. 14, p. 1.Google Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.Baikal Institute of Nature ManagementSiberian Branch of the Russian Academy of SciencesUlan-UdeRussian Federation
  2. 2.Buryat State UniversityUlan-UdeRussian Federation

Personalised recommendations