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Synthesis and properties of hyperbranched polyester polyacrylic acids and their metal complexes

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Abstract

New polydentate ligands based on the hyperbranched third generation polyesters containing terminal acrylic acid fragments were synthesized. The ionization and complexation parameters of new compounds in solution were estimated by spectrophotometry and pH-metric titration followed by experimental data processing using mathematical simulation by the CPESSP program. The procedure for the synthesis was proposed. The polynuclear cobalt(II), nickel(II), and copper(II) complexes with polyester polycarboxylates were synthesized.

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Authors and Affiliations

  1. Kazan (Volga Region) Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    M. P. Kutyreva, N. A. Ulakhovich, A. R. Gataulina, A. A. Khannanov, O. A. Malinovskikh & E. P. Medyantseva

  2. E. K. Zavoisky Physical Technical Institute, Kazan Scientific Center of the Russian Academy of Sciences, 10/7 ul. Sibirsky trakt, 420029, Kazan, Russian Federation

    S. V. Yurtaeva

Authors
  1. M. P. Kutyreva
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  2. N. A. Ulakhovich
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  3. A. R. Gataulina
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  4. A. A. Khannanov
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  5. O. A. Malinovskikh
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  6. S. V. Yurtaeva
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  7. E. P. Medyantseva
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Corresponding author

Correspondence to M. P. Kutyreva.

Additional information

Dedicated to Academician of the Russian Academy of Sciences A. I. Konovalov on the occasion of his 80th anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0239–0246, January, 2014.

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Kutyreva, M.P., Ulakhovich, N.A., Gataulina, A.R. et al. Synthesis and properties of hyperbranched polyester polyacrylic acids and their metal complexes. Russ Chem Bull 63, 239–246 (2014). https://doi.org/10.1007/s11172-014-0419-8

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  • DOI: https://doi.org/10.1007/s11172-014-0419-8

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