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Russian Chemical Bulletin

, Volume 63, Issue 1, pp 239–246 | Cite as

Synthesis and properties of hyperbranched polyester polyacrylic acids and their metal complexes

  • M. P. Kutyreva
  • N. A. Ulakhovich
  • A. R. Gataulina
  • A. A. Khannanov
  • O. A. Malinovskikh
  • S. V. Yurtaeva
  • E. P. Medyantseva
Full Articles

Abstract

New polydentate ligands based on the hyperbranched third generation polyesters containing terminal acrylic acid fragments were synthesized. The ionization and complexation parameters of new compounds in solution were estimated by spectrophotometry and pH-metric titration followed by experimental data processing using mathematical simulation by the CPESSP program. The procedure for the synthesis was proposed. The polynuclear cobalt(II), nickel(II), and copper(II) complexes with polyester polycarboxylates were synthesized.

Key words

hyperbranched polyester polyacrylic acids metal complexes ionization and complexation parameters 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • M. P. Kutyreva
    • 1
  • N. A. Ulakhovich
    • 1
  • A. R. Gataulina
    • 1
  • A. A. Khannanov
    • 1
  • O. A. Malinovskikh
    • 1
  • S. V. Yurtaeva
    • 2
  • E. P. Medyantseva
    • 1
  1. 1.Kazan (Volga Region) Federal UniversityKazanRussian Federation
  2. 2.E. K. Zavoisky Physical Technical InstituteKazan Scientific Center of the Russian Academy of SciencesKazanRussian Federation

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