Skip to main content
SpringerLink
Log in

Au-Ni and Au-Fe heterometallic systems: an X-ray photoelectron spectroscopy study

  • Reviews
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Results of X-ray photoelectron spectroscopy (XPS) studies of Au-Ni and Au-Fe bimetallic nanoparticles (in the form of black and supported on SiO2) are considered and systematized. The nanoparticles studied were prepared by metal-vapor synthesis. XPS studies on the chemical compositions, structures, and electronic states of heterometallic nanocomposites carried out both in the traditional and differential charging mode with a bias voltage applied to the sample holder are analyzed. The effect of the composition and electronic state of the Au-Ni heterometallic system on its catalytic activity is studied. It was shown that the variable differential charging mode allows one to identify and characterize species of different nature in multi-component heterometallic nanostructured materials. A state which correlates with the catalytic activity of the Au-Ni/SiO2 system was identified in the Au 4f photoelectron spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. P. Felicissimo, O. N. Martyanov, T. Risse, H.-J. Freund, Surf. Sci., 2007, 601, 2105.

    Article  CAS  Google Scholar 

  2. I. P. Suzdalev, Yu. V. Maksimov, A. Yu. Vasil’kov, A. V. Naumkin, V. L. Podshibikhin, I. O. Volkov, Ros. nano-tekhnologii, 2008, 3, 76 [Nanotechnologies in Russia (Engl. Transl.), 2008, 3, 72].

    Google Scholar 

  3. A. V. Naumkin, A. Yu. Vasil’kov, V. L. Podshibikhin, I. O. Volkov, I. P. Suzdalev, Yu. V. Maksimov, S. V. Novichikhin, V. V. Matveev, V. K. Imshennik, Zh. Fiz. Khim., 2011, 85, 713 [Russ. J. Phys. Chem. A (Engl. Transl.), 2011, 85, 636].

    Google Scholar 

  4. J. L. Rousset, F. J. Cadete Santos Aires, B. R. Sekhar, P. Melinon, B. Prevel, M. Pellarin, J. Phys. Chem. B, 2000, 104, 5430.

    Article  CAS  Google Scholar 

  5. M. A. Keane, S. Gómez-Quero, F. Cárdenas-Lizana, W. Shen, ChemCatChem, 2009, 1, 270.

    Article  CAS  Google Scholar 

  6. F. Cárdenas-Lizana, M. A. Keane, J. Mater. Sci., 2013, 48, H543.

    Article  Google Scholar 

  7. L. Zhao, N. Heinig, K. T. Leung, J. Phys. Chem. C, 2012, 116, 12322.

    Article  CAS  Google Scholar 

  8. L. Guczi, D. Horvath, Z. Paszti, L. Toth, Z. E. Horvath, A. Karacs, G. Peto, J. Phys. Chem. B, 2000, 104, 3183.

    Article  CAS  Google Scholar 

  9. S. Zafeiratos, S. Kennou, J. Phys. Chem. B, 2002, 106, 41.

    Article  CAS  Google Scholar 

  10. F. Cárdenas-Lizana, S. Gómez-Quero, G. Jacobs, Y. Ji, B. H. Davis, L. Kiwi-Minsker, M. A. Keane, J. Phys. Chem. C, 2012, 116, 11166.

    Article  Google Scholar 

  11. Y. Matsumura, K. Kagawa, Y. Usami, Chem. Commun., 1997, 657.

    Google Scholar 

  12. R. Mu, Q. Fu, H. Xu, H. Zhang, Y. Huang, Z. Jiang, S. Zhang, D. Tan, X. Bao, J. Am. Chem. Soc., 2011, 133, 1978.

    Article  CAS  Google Scholar 

  13. M. Kang, M. W. Song, T. W. Kim, K. L. Kim, Can. J. Chem. Eng., 2002, 80, 63.

    Article  CAS  Google Scholar 

  14. V. I. Bukhtiyarov, I. P. Prosvirin, R. I. Kvon, J. Electron. Spectrosc. Relat. Phenom., 1977, 77, 7.

    Article  Google Scholar 

  15. M. Yu. Smirnov, A. V. Kalinkin, A. A. Dubkov, E. I. Vovk, A. M. Sorokin, A. I. Nizovskii, B. Carberry, V. I. Bukhtiyarov, Kinet. Katal., 2011, 52, 605 [Kinet. Catal. (Engl. Transl.), 2011, 52, 595].

    Article  Google Scholar 

  16. M. Yu. Smirnov, A. V. Kalinkin, A. A. Dubkov, E. I. Vovk, A. M. Sorokin, A. I. Nizovskii, B. Carberry, V. I. Bukhtiyarov, Kinet. Katal., 2008, 49, 876 [Kinet. Catal. (Engl. Transl.), 2008, 49, 831].

    Google Scholar 

  17. B. J. Tan, P. M. A. Sherwood, K. J. Klabunde, Langmuir, 1990, 6, 105.

    Article  CAS  Google Scholar 

  18. A. Yu. Vasil’kov, A. V. Naumkin, I. O. Volkov, V. L. Podshibikhin, G. V. Lisichkin, A. R. Khokhlov, Surf. Interface Anal., 2010, 42, 559.

    Article  Google Scholar 

  19. A. V. Naumkin, A. P. Krasnov, E. E. Said-Galiev, A. Y. Nikolaev, I. O. Volkov, O. V. Afonicheva, V. A. Mit’, A. R. Khokhlov, in Unique Properties of Polymers and Composites: Pure and Applied Science Today and Tomorrow, Eds Y. N. Bubnov, V. A. Vasnev, A. A. Askaskii, G. E. Zaikov, Nova Sci. Publ., New York, 2012, Vol. 2, p. 293.

  20. A. Yu. Vasil’kov, B. A. Zachernyuk, Z. N. Karpikov, I. O. Volkov, Ya. V. Zubavichus, A. A. Veligzhanin, A. A. Chernyshov, M. I. Buzin, L. N. Nikitin, V. I. Nedel’kin, Zh. Prikl. Khim., 2007, 80, 2058 [Russ. J. Appl. Chem. (Engl. Transl.), 2007, 80, 2136].

    Google Scholar 

  21. V. V. Smirnov, S. A. Nikolaev, G. P. Murav’eva, L. A. Tyu- rina, A. Yu. Vasil’kov, Kinet. Katal., 2007, 48, 281 [Kinet. Catal. (Engl. Transl.), 2007, 48, 265].

    Google Scholar 

  22. A. P. Krasnov, V. N. Aderikha, O. V. Afonicheva, V. A. Mit’, N. N. Tikhonov, A. Yu. Vasil’kov, E. E. Said-Galiev, A. V. Naumkin, A. Yu. Nikolaev, Trenie i Iznos, 2010, 31, 93 [J. Frict. Wear (Engl. Transl.), 2010, 31, 68].

    CAS  Google Scholar 

  23. A. V. Naumkin, A. Yu. Vasil’kov, I. O. Volkov, V. V. Smirnov, S. A. Nikolaev, Neorg. Mat., 2007, 43, 445 [Inorg. Mater. (Engl. Transl.), 2007, 43, 381].

    Google Scholar 

  24. S. A. Nikolaev, V. V. Smirnov, I. P. Beletskaya, A. Yu. Vasil’kov, A. V. Naumkin, L. A. Tyurina, Ros. nanotekhnologii, 2007, 2, 58 [Nanotechnologies in Russia (Engl. Transl.), 2007, 2, 58].

    Google Scholar 

  25. A. Yu. Vasil’kov, S. A. Nikolaev, V. V. Smirnov, A. V. Naumkin, I. O. Volkov, V. L. Podshibikhin, Mendeleev Commun., 2007, 17, 268.

    Article  Google Scholar 

  26. S. B. Dicenzo, S. D. Berry, E. H. Hartford, Jr., Phys. Rev. B: Condens. Matter, 1988, 38, 8465.

    Article  Google Scholar 

  27. A. K. Santra, D. W. Goodman J. Phys. Condens. Matter, 2002, 14, R31.

    Google Scholar 

  28. S. A. Nikolaev, A. Yu. Vasil’kov, V. V. Smirnov, L. A. Tyurina, Kinet. Katal., 2005, 46, 915 [Kinet. Cat. (Engl. Transl.), 2005, 46, 867].

    Article  Google Scholar 

  29. G. K. Wertheim, S. B. Dicenzo, S. E. Youngquist, Phys. Rev. Lett., 1983, 51, 2310.

    Article  CAS  Google Scholar 

  30. A. G. Rybkin, D. Yu. Usachev, A. Yu. Varykhalov, A. M. Shikin, V. K. Adamchuk, Fiz. Tverdogo Tela, 2007, 49, 933 [Phys. Solid State (Engl. Transl.), 2007, 49, 984].

    Google Scholar 

  31. P. Steiner, S. Hüfner, Solid State Commun., 1981, 37, 279.

    Article  CAS  Google Scholar 

  32. T. Okazawa, M. Fujiwara, T. Nishimura, T. Akita, M. Kohyama, Y. Kido, Surf. Sci., 2006, 600, 1331.

    Article  CAS  Google Scholar 

  33. A. A. Veligzhanin, E. V. Guseva, Ya. V. Zubavichus, A. L. Trigub, A. A. Chernyshov, O rabote stantsii “Strukturnoe materialovedenie” Kurchatovskogo istochnika sinkhrotronnogo izlucheniya v 2006 g. [Structural Materials Science Station, Kurchatov Source of Synchrotron Radiation: Results Obtained in 2006], Russian Research Center “Kurchatov Institute”, Preprint IAE-6453/9, Moscow, 2007, 67 pp. (in Russian).

    Google Scholar 

  34. A. V. Naumkin, A. Kraut-Vass, S. W. Gaarenstroom, C. J. Powell, NIST X-ray Photoelectron Spectroscopy Database, Version 4.1, National Institute of Standards and Technology, Gaithersburg, 2012; http://srdata.nist.gov/xps/.

    Google Scholar 

  35. Y. X. Li, K. J. Klabunde, Hyperfine Interact., 1988, 41, 665.

    Article  CAS  Google Scholar 

  36. N. S. McIntyre, D. G. Zetaruk, Anal. Chem., 1977, 49, 1521.

    Article  CAS  Google Scholar 

  37. A. P. Grosvenor, B. A. Kobe, M. C. Biesinger, N. S. Mc-Intyre, Surf. Interface Anal., 2004, 36, 1564.

    Article  CAS  Google Scholar 

  38. D. C. Frost, C. F. McDowell, I. S. Woolsey, Chem. Phys. Lett., 1972, 17, 320.

    Article  CAS  Google Scholar 

  39. R. Davies, D. Edwards, J. Gräfe, L. Gilbert, P. Davies, G. Hutchings, M. Bowker, Surf. Sci., 2011, 605, 1754.

    Article  CAS  Google Scholar 

  40. X. Deng, J. Lee, C. Matranga, Surf. Sci., 2010, 604, 627.

    Article  CAS  Google Scholar 

  41. C. J. Pastor, C. Limones, J. J. Hinarejos, J. M. Garcia, R. Miranda, J. Gomez-Goni, J. E. Ortega, H. D. Abruna, Surf. Sci., 1996, 364, L505.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, Moscow, 119991, Russian Federation

    A. V. Naumkin & A. Yu. Vasil’kov

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Bldg. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    A. Yu. Vasil’kov

Authors
  1. A. V. Naumkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Yu. Vasil’kov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Naumkin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2559–2566, December, 2013.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Naumkin, A.V., Vasil’kov, A.Y. Au-Ni and Au-Fe heterometallic systems: an X-ray photoelectron spectroscopy study. Russ Chem Bull 62, 2559–2566 (2013). https://doi.org/10.1007/s11172-013-0373-x

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-013-0373-x

Key words

Search

Navigation