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Russian Chemical Bulletin

, Volume 62, Issue 11, pp 2472–2476 | Cite as

Reactions of activated organonickel σ-complexes with elemental (white) phosphorus

  • D. G. Yakhvarov
  • S. V. Kvashennikova
  • O. G. Sinyashin
Full Articles

Abstract

The reactivity of organonickel σ-complexes of the type [NiBr(Ar)(bpy)] (Ar is 2,4,6-tri-methylphenyl (Mes) or 2,4,6-triisopropylphenyl (Tipp); bpy is 2,2′-bipyridine) toward elemental (white) phosphorus was studied. For the reaction to occur, the complexes must be activated by removal of the bromide anion from the coordination sphere of nickel. This can be achieved either in the presence of halogen scavengers or by electrochemical reduction. The arylphosphinic acids ArP(O)(OH)H formed by hydrolysis of organic nickel phosphides are the major reaction products of the overall process.

Key words

arylphosphinic acids white phosphorus organonickel σ-complexes organic phosphides electrochemical activation 

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • D. G. Yakhvarov
    • 1
    • 2
  • S. V. Kvashennikova
    • 1
  • O. G. Sinyashin
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Research Center of the Russian Academy of SciencesKazanRussian Federation
  2. 2.Kazan Federal UniversityKazanRussian Federation

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