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Russian Chemical Bulletin

, Volume 62, Issue 8, pp 1843–1851 | Cite as

Synthesis, structure, and properties of polynuclear molybdenum(v,vi) oxomethoxides with magnesium

  • Yu. V. Manakin
  • D. A. Kuznetsov
  • I. V. Fedyanin
  • K. A. Lyssenko
  • N. V. Kovaleva
  • A. V. Kulikov
  • T. A. Bazhenova
Full Articles

Abstract

General conditions for the formation of heterometallic clusters by the simultaneous methanolysis of MoCl5 and MgCl2 were determined. The resultant alkalinity of the reaction solution, the Mg/Mo molar ratio, and the presence of traces of water are key factors responsible for the composition and structure of the mixed magnesium molybdenum methoxides that formed. The new decanuclear mixed-valence MoV,VI Mg oxomethoxide [MoV 4O43-O)22-O)2MoVI 2-O4(OMe)2Mg4(MeOH)63-OMe)62-OMe)8] (1) was synthesized by the reaction of lowernuclearity magnesium molybdenum oxoalkoxide complexes: NaMoV of the complex Na(MeOH)MoV 2O22-OMe)3(OMe)4 (2) and MgMoVI of the complex [MoVIO2Mg(MeOH)2-(OMe)4]2 (3). The molecular structure of 1 was determined by X-ray diffraction.

Key words

magnesium molybdenum oxoalkoxides crystal and molecular structures bimetallic alkoxides 

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References

  1. 1.
    T. A. Bazhenova, A. E. Shilov, Coord. Chem. Rev., 1995, 114, 69.CrossRefGoogle Scholar
  2. 2.
    L. P. Didenko, A. E. Shilov, A. K. Shilova, Kinet. Katal., 1979, 1488 [Kinet. Catal. (Engl. Transl.), 1979, 20].Google Scholar
  3. 3.
    A. E. Shilov, in Electron Transfer in Chemistry, Ed. V. Balzani, Wiley-VCH, Weinheim, 2001, 899.Google Scholar
  4. 4. (a)
    N. T. Denisov, N. I. Shuvalova, React. Kinet. Catal. Lett., 1976, 4, 431CrossRefGoogle Scholar
  5. 4. (b)
    N. T. Denisov, A. I. Korosteleva, Yu. I. Morozov, S. I. Kobeleva, Kinet. Katal., 1977, 758 [Kinet. Catal. (Engl. Transl.), 1977, 18].Google Scholar
  6. 5.
    T. A. Bazhenova, K. A. Lyssenko, D. A. Kuznetsov, N. V. Kovaleva, Y. V. Manakin, T. A. Savinykh, A. F. Shestakov, J. Chem. Soc., Dalton Trans., 2013, submitted.Google Scholar
  7. 6.
    G. M. Sheldrick, Acta Crystallogr., Sect. A, 2007, 64, 112.CrossRefGoogle Scholar
  8. 7.
    F. H. Allen, Acta Crystallogr., Sect. B, 2002, 58, 380.CrossRefGoogle Scholar
  9. 8.
    N. V. Bardina, T. A. Bazhenova, K. A. Lissenko, M. Yu. Antipin, Yu. M. Shulga, T. A. Filina, A. F. Shestakov, Mendeleev Commun., 2006, 16, 307.CrossRefGoogle Scholar
  10. 9.
    C. Limberg, A. J. Downs, A. J. Blake, S. Parsons, Inorg. Chem., 1996, 35, 4439.CrossRefGoogle Scholar
  11. 10.
    K. J. Moynihan, P. M. Boorman, J. M. Ball, V. D. Patel, K. A. Kerr, Acta Crystallogr., Sect. B, 1982, 38, 2258.CrossRefGoogle Scholar
  12. 11.
    M. Yu. Antipin, Yu. T. Struchkov, A. E. Shilov, A. K. Shilova, Gazz. Chim. Ital., 1993, 123, 265.Google Scholar
  13. 12.
    V. G. Kessler, Chem. Commun., 2003, 1213.Google Scholar
  14. 13.
    J. A. Ibers, Nature, 1963, 197, 686.CrossRefGoogle Scholar
  15. 14.
    S. A. Al’tshuler, B. M. Kozyrev, EPR soedinenii elementov promezhutochnykh grupp [ESR of Compounds of Intermediate-Group Elements], Nauka, Moscow, 1972, 672 pp (in Russian).Google Scholar
  16. 15.
    D. L. Kepert, Inorg. Chem., 1969, 8, 1556.CrossRefGoogle Scholar
  17. 16.
    B. Modec, Yu. V. Brencic, J. Zubieta, J. Chem. Soc., Dalton Trans., 2002, 1500.Google Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Yu. V. Manakin
    • 1
  • D. A. Kuznetsov
    • 1
  • I. V. Fedyanin
    • 2
  • K. A. Lyssenko
    • 2
  • N. V. Kovaleva
    • 1
  • A. V. Kulikov
    • 1
  • T. A. Bazhenova
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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