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Russian Chemical Bulletin

, Volume 62, Issue 6, pp 1382–1387 | Cite as

1,3-Dipolar cycloaddition reaction of nitrone η6-(arene)chromium tricarbonyl complexes with styrene and η6-(styrene)chromium tricarbonyl

  • A. N. Artemov
  • E. V. Sazonova
  • N. Yu. Zarovkina
Full Articles

Abstract

The products of 1,3-dipolar cycloaddition of the nitrone-type η6-(arene)chromium tricarbonyl complexes (CO)3CrC6H5CH=N+(O)R, where R = Me, Ph, But, with styrene and η6-(styrene)chromium tricarbonyl were obtained and characterized by a combination of physicochemical methods. This type of reactions proceeded with very high regio- and stereoselectivity to exclusively form cis-2,3,5-tri-substituted isoxazolidines.

Key words

nitrone η6-(arene)chromium tricarbonyl isoxazolidine 1,3-dipolar cycloaddition 

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • A. N. Artemov
    • 1
  • E. V. Sazonova
    • 1
  • N. Yu. Zarovkina
    • 1
  1. 1.N. I. Lobachevsky State University of Nizhny NovgorodNizhny NovgorodRussian Federation

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