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1,3-Dipolar cycloaddition reaction of nitrone η6-(arene)chromium tricarbonyl complexes with styrene and η6-(styrene)chromium tricarbonyl

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Abstract

The products of 1,3-dipolar cycloaddition of the nitrone-type η6-(arene)chromium tricarbonyl complexes (CO)3CrC6H5CH=N+(O−)R, where R = Me, Ph, But, with styrene and η6-(styrene)chromium tricarbonyl were obtained and characterized by a combination of physicochemical methods. This type of reactions proceeded with very high regio- and stereoselectivity to exclusively form cis-2,3,5-tri-substituted isoxazolidines.

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Authors and Affiliations

  1. N. I. Lobachevsky State University of Nizhny Novgorod, 23 korp. 5 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    A. N. Artemov, E. V. Sazonova & N. Yu. Zarovkina

Authors
  1. A. N. Artemov
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  2. E. V. Sazonova
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  3. N. Yu. Zarovkina
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Correspondence to N. Yu. Zarovkina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1382–1387, June, 2013.

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Artemov, A.N., Sazonova, E.V. & Zarovkina, N.Y. 1,3-Dipolar cycloaddition reaction of nitrone η6-(arene)chromium tricarbonyl complexes with styrene and η6-(styrene)chromium tricarbonyl. Russ Chem Bull 62, 1382–1387 (2013). https://doi.org/10.1007/s11172-013-0197-8

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  • DOI: https://doi.org/10.1007/s11172-013-0197-8

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